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Ultrasound-Assisted Synthesis of C60 Fullerene-Fused 1,4-Oxathian-2-ones

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Abstract

Previously unknown C60 fullerene-fused 1,4-oxathian-2-ones 1,9-[2′-oxo-1′,4′-oxathiano]-1,9-dihydro-(C60-Ih)[5,6]fullerene and 1,9-[3′-Methyl-2′-oxo-1′,4′-oxathiano]-1,9-dihydro-(C60-Ih)[5,6]fullerene were obtained by a selective reaction mercaptocarboxylic acids (mercaptoacetic and 2-mercaptopropionic) with fullerene epoxide C60O in the presence of NaOH in an inert atmosphere at room temperature under ultrasonication for 1 h. The yields of the target product were estimated at 96 and 87%, respectively (by HPLC). A plausible reaction mechanism for was proposed.

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ACKNOWLEDGMENTS

The structural studies were conducted at the “Agidel” Center for Collective Use, Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences.

Funding

The work was funded by the Ministry for Education and Science of the Russian Federation in the framework of the State order (topic FMRS-2022-0077).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia

    Z. S. Kinzyabaeva

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  1. Z. S. Kinzyabaeva
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Correspondence to Z. S. Kinzyabaeva.

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Kinzyabaeva, Z.S. Ultrasound-Assisted Synthesis of C60 Fullerene-Fused 1,4-Oxathian-2-ones. Russ J Gen Chem 93 (Suppl 1), S131–S136 (2023). https://doi.org/10.1134/S1070363223140219

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