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Effective Single-Reactor Synthesis of Dithiocarbamates and Investigation of Their Flotation Properties

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Abstract

The reaction of n-butylamine with carbon disulfide in the presence of NaOH followed by the reaction with 2-chloroethanol or benzоyl chloride leads to the formation of previously unknown S-organyl-N-butyldithiocarbamates in 83–92% yield. The flotation activity of 2-hydroxyethylbutyldithiocarbamate as an additional collector in the flotation of gold-bearing sulfide ore was studied.

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Funding

The work was carried out using the equipment of the Baikal Analytical Center for Collective Use of the Siberian Branch of the Russian Academy of Sciences. The study was carried out with financial support from the Russian Science Foundation (project no. 22-77-00009).

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Authors and Affiliations

  1. Irkutsk National Research Technical University, 664074, Irkutsk, Russia

    А. Е. Burdonov & Т. Kh. Sakhabutdinova

  2. Irkutsk State University, 664003, Irkutsk, Russia

    I. B. Rozentsveig

  3. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 664033, Irkutsk, Russia

    I. B. Rozentsveig, V. G. Fedoseeva, Е. А. Verochkina, L. I. Larina & N. V. Vchislo

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  1. А. Е. Burdonov
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  2. Т. Kh. Sakhabutdinova
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  3. I. B. Rozentsveig
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  4. V. G. Fedoseeva
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  5. Е. А. Verochkina
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  7. N. V. Vchislo
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Correspondence to N. V. Vchislo.

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I.B. Rozentsveig is the Guest Editor of the Special Issue of the Russian Journal of General Chemistry. The remaining authors declare no conflict of interest.

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To the 85th Anniversary of B.A. Trofimov

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Burdonov, А.Е., Sakhabutdinova, Т.K., Rozentsveig, I.B. et al. Effective Single-Reactor Synthesis of Dithiocarbamates and Investigation of Their Flotation Properties. Russ J Gen Chem 93 (Suppl 1), S198–S202 (2023). https://doi.org/10.1134/S1070363223140116

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  • DOI: https://doi.org/10.1134/S1070363223140116

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