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Membrane Transport of Polyfunctional Substrates by Alkyl (N-Alkyl-N,N-dioctylammoniomethyl) Phosphonates

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Abstract

The membrane transport properties of phosphorylated betaines with respect to mono- and polyfunctional carboxylic acids were studied. The structure of the transferred H-complexes was discussed; by means of IR spectroscopy, the main coordination centers of the carriers were identified. Using the method of quantum chemical calculations, a relationship between the substrate flux and lipophilicity and the structure of the resulting H-complexes was shown.

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Funding

This study was financially supported by the Russian Science Foundation (project no. 22-23-00335, https://rscf.ru/project/2-23-00335/).

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Authors and Affiliations

  1. Kazan (Volga Region) Federal University, 420088, Kazan, Russia

    N. V. Davletshina, E. A. Ermakova, A. R. Khabibullina, D. R. Dolgova, T. R. Gimadiev, R. R. Davletshin, I. I. Stoikov & R. A. Cherkasov

Authors
  1. N. V. Davletshina
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  2. E. A. Ermakova
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  3. A. R. Khabibullina
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  4. D. R. Dolgova
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  5. T. R. Gimadiev
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  6. R. R. Davletshin
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  7. I. I. Stoikov
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  8. R. A. Cherkasov
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Correspondence to N. V. Davletshina.

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Davletshina, N.V., Ermakova, E.A., Khabibullina, A.R. et al. Membrane Transport of Polyfunctional Substrates by Alkyl (N-Alkyl-N,N-dioctylammoniomethyl) Phosphonates. Russ J Gen Chem 93, 3114–3122 (2023). https://doi.org/10.1134/S1070363223120101

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