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Chemical Stability of Pb[(UO2)2O2(OH)2](H2O) and Pb2[(UO2)5O6(OH)2](H2O)2 Compounds in Aqueous Solutions

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Abstract

The chemical stability of Pb[(UO2)2O2(OH)2](H2O) and Pb2[(UO2)5O6(OH)2](H2O)2 compounds in aqueous solutions was studied. The acid-base boundaries of the existence of these compounds in aqueous solutions were established, the hydrolysis products were identified, and their solubility was determined. Based on the data obtained, the equilibrium constants of dissolution reactions, the Gibbs functions of the formation and dissolution of Pb[(UO2)2O2(OH)2](H2O) and Pb2[(UO2)5O6(OH)2](H2O)2 were calculated, the solubility curves of the compounds under study, and the phase diagrams of U(VI) and Pb(II) in saturated aqueous solutions and in equilibrium solid phases were constructed.

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REFERENCES

  1. Zhang, Y., Lu, K.T., and Zheng, R., Dalton Trans., 2022, vol. 21, p. 2158. https://doi.org/10.1039/d1dt03916d

    Article  CAS  Google Scholar 

  2. Baker, J.R., Coord. Chem. Rev., 2013, vols. 266–267, p. 123. https://doi.org/10.1016/j.ccr.2013.10.004

    Article  CAS  Google Scholar 

  3. Sino, M.C.A. and Grambow, B., Radiochim. Acta, 1994, vols. 66–67, p. 37. https://doi.org/10.1524/ract.1994.6667.s1.37

    Article  Google Scholar 

  4. Sowder, A.G., Clark, S.B., and Fjeld, R.A., Radiochim. Acta, 1996, vol. 74, p. 45. https://doi.org/10.1524/ract.1996.74.special-issue.45

  5. Sowder, A.G., Clark, S.B., and Fjeld, R.A., Environ. Sci. Technol., 1999, vol. 33, p. 3552. https://doi.org/10.1021/es9901516

    Article  CAS  Google Scholar 

  6. Brugger, J., Krivovichev, S.V., Berlepsch, P., Meisser, N., Ansermet, S., and Armbruster, T., Am. Mineral., 2004, vol. 89, p. 339. https://doi.org/10.2138/am-2004-2-312

    Article  CAS  Google Scholar 

  7. Protas, J., Compt. Rend., 1957, vol. 244, p. 2942.

    CAS  Google Scholar 

  8. Fleischer, M., Am. Mineral., 1957, vol. 42, p. 919.

    Google Scholar 

  9. Deliens, M., Mineral. Mag., 1977, vol. 41, p. 51.

    Article  CAS  Google Scholar 

  10. Burns, P.C., Am. Mineral., 1999, vol. 84, p. 1661.

    Article  CAS  Google Scholar 

  11. Plasil, J., Bull. Mineral. Petrolog., 2020, vol. 28, no. 2, p. 322. https://doi.org/10.46861/bmp.28.322

    Article  Google Scholar 

  12. Piret, P., Deliens, M., Piret-Meunier, J., and Germain, G., Bull. Mineral., 1983, vol. 106, p. 299. https://doi.org/10.3406/bulmi.1983.7709

    Article  CAS  Google Scholar 

  13. Schoep, A., Compt. Rend., 1921, vol. 173, p. 1186.

    CAS  Google Scholar 

  14. Palache, C., Am. Mineral., 1934, vol. 19, p. 309.

    Google Scholar 

  15. Mereiter, K., Tscher. Miner. Petrog., 1979, vol. 26, p. 279.

    Article  CAS  Google Scholar 

  16. Taylor, J.C., Stuart, W.L., and Mumme, I.A., J. Inorg. Nucl. Chem., 1981, vol. 43, no. 10, p. 2419.

    Article  CAS  Google Scholar 

  17. Čejka, J., Muck, A., and Urbanec, Z., Thermochim. Acta, 1985, vol. 93, p. 637. https://doi.org/10.1016/0040-6031(85)85160-1

    Article  Google Scholar 

  18. Li, Y. and Burns, P.C., Can. Mineral., 2000, vol. 38, p. 727.

    Article  CAS  Google Scholar 

  19. Schindler, M., Mandaliev, P., Hawthorne, F.C., and Putnis, A., Can. Mineral., 2006, vol. 44, p. 415.

    Article  CAS  Google Scholar 

  20. Frost, R.L., Čejka, J., Ayoko, G.A., and Weier, M.L., Polyhedron, 2007, vol. 26, p. 3724. https://doi.org/10.1016/j.poly.2007.04.023

    Article  CAS  Google Scholar 

  21. Frost, R.L., Čejka, J., and Weier, M.L., J. Raman Spectrosc., 2007, vol. 38, p. 460. https://doi.org/10.1002/jrs.1669

    Article  CAS  Google Scholar 

  22. Burns, P.C. and Hanchar, J.M., Can. Mineral., 1999, vol. 37, p. 1483.

    CAS  Google Scholar 

  23. Piret, P., Bull. Mineral., 1985, vol. 108, p. 659. https://doi.org/10.3406/bulmi.1985.7882

  24. Li, Y. and Burns, P.C., Can. Mineral., 2000, vol. 38, p. 737.

    Article  CAS  Google Scholar 

  25. Schindler, M. and Hawthorne, F.C., Can. Mineral., 2007, vol. 45, p. 963. https://doi.org/10.2113/gscanmin.45.4.963

    Article  CAS  Google Scholar 

  26. Li, Y. and Burns, P.C., Can. Mineral., 2000, vol. 38, p. 1433.

    Article  CAS  Google Scholar 

  27. Burns, P.C., Am. Mineral., 1997, vol. 82, p. 1176.

    Article  CAS  Google Scholar 

  28. Bartlett, J.R. and Cooney, R.P., J. Mol. Struct., 1989, vol. 193, p. 295.

    Article  CAS  Google Scholar 

  29. Vochten, R. and Haverbeke, L., Mineral. Petrol., 1990, vol. 43, p. 65.

    Article  CAS  Google Scholar 

  30. Navrotsky, A., Shvareva, T., Guo, X., and Rock, P.A., Mineralogical Association of Canada Short, Winnipeg MB, 2013, Ch. 4, p. 1.

  31. Chernorukov, N.G., Nipruk, O.V., Abrazheev, R.V., and Chaplieva, K.A., Russ. J. Gen. Chem., 2016, vol. 86, no. 9, p. 1987. https://doi.org/10.1134/S1070363216090024

    Article  CAS  Google Scholar 

  32. Kovba, L.M., Radiokhimiya, 1972, vol. 14, p. 727.

  33. Guillaumont, R., Fanghänel, T., Fuger, J., Grenthe, I., Neck, V., Palmer, D.A., and Rand, M.H., Update on the Chemical Thermodynamics of Uranium, Neptunium, and Plutonium, Amsterdam: Elsevier, 2003.

  34. Grenthe, I., Fuger, J., Koning, R., Konings, R.J.M., Lemire, R.J., Muller, A.B., Nguyen-Trung, C., and Wanner, H., Chemical Thermodynamics of Uranium, Amsterdam: North-Holland, 2004.

  35. Termicheskie konstanty veshchestv (Thermal Constants of Substances), Glushko. V.P., Ed., Moscow: USSR Academy of Sciences, vols. I–X, 1965–1981.

  36. Gorman-Lewis, D., Burns, P.C., and Fein, J.B., J. Chem. Thermodyn., 2008, vol. 40, p. 335. https://doi.org/10.1016/j.jct.2007.12.004

    Article  CAS  Google Scholar 

  37. Nipruk, O.V., Chernorukov, N.G., and Chaplieva, K.A., J. Radioanal. Nucl. Chem., 2017, vol. 314 (2), p. 1405. https://doi.org/10.1007/s10967-017-5462-0

    Article  CAS  Google Scholar 

  38. Chernorukov, N.G, Nipruk, O.V., Klinshova, K.A., Tumaeva, O.N., and Sokolov, D.V., New J. Chem., 2021, vol. 45, p. 9922. https://doi.org/10.1039/D1NJ01414E

    Article  CAS  Google Scholar 

  39. Markov, V.K., Vernyi, E.A., Vinogradov, A.V., Elinson, S.V., Klygin, A.E., and Moiseev, I.V., Uran. Metody ego opredeleniya (Uranium. Methods for its Determination), Moscow: Atomizdat, 1964.

  40. Polyanskii, N.G., Analiticheskaya khimiya elementov. Svinets (Analytical Chemistry of Elements. Lead), Moscow: Nauka, 1986.

  41. Kiseleva, E.K. and Suslennikova, V.M., Spravochnoe rukovodstvo po prigotovleniyu titrov rastvorov i ustanovke ikh titrov (Reference Guide for Preparing Solution Titers and Determining their Titers), Leningrad: Tippolitografiya LKVVIA im. A.F. Mozhaiskogo, 1959.

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Funding

The work was carried out with the financial support of the Ministry of Education and Science of the Russian Federation (basic part of the state task, project no. FSWR-2023-0025).

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Authors and Affiliations

  1. Lobachevsky State University of Nizhni Novgorod, 603022, Nizhni Novgorod, Russia

    O. V. Nipruk, K. A. Klinshova, G. N. Chernorukov, A. A. Denisova & R. V. Abrazheev

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  1. O. V. Nipruk
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  2. K. A. Klinshova
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  3. G. N. Chernorukov
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  4. A. A. Denisova
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Correspondence to O. V. Nipruk.

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Nipruk, O.V., Klinshova, K.A., Chernorukov, G.N. et al. Chemical Stability of Pb[(UO2)2O2(OH)2](H2O) and Pb2[(UO2)5O6(OH)2](H2O)2 Compounds in Aqueous Solutions. Russ J Gen Chem 93, 2549–2559 (2023). https://doi.org/10.1134/S1070363223100109

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