Skip to main content
SpringerLink
Log in

New Europium Methoxycinnamates: Synthesis and Thermal and Luminescence Properties

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

A method was proposed for the synthesis of Eu(III) compounds with para-methoxycinnamic acid anions and neutral ligands, starting from the sodium salt of para-methoxycinnamic acid. Using the methods of chemical elemental and thermal analyses and IR spectroscopy, the composition of the complexes and the coordination mode of carboxylate anions were determined. It was found that europium(III) methoxycinnamate with hexamethylphosphotriamide has the highest luminescence intensity. Luminescent polymer materials with synthesized europium(III) methoxycinnamates were obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

REFERENCES

  1. Bunzli, J.-C.G. and Eliseeva, S.V., Chem. Sci., 2013, vol. 4, no. 5, p. 1939. https://doi.org/10.1039/C3SC22126A

    Article  CAS  Google Scholar 

  2. Deacon, G.B., Forsyth, C.M., Junk, P.C., and Leary, S.G., Z. anorg. allg. Chem., 2008, vol. 634, no. 1, p. 91. https://doi.org/10.1002/zaac.200700359

    Article  CAS  Google Scholar 

  3. Nikolaev, A.A., Kulyasov, A.N., and Panyushkin, V.T., Russ. J. Gen. Chem., 2020, vol. 90, p. 2498. https://doi.org/10.1134/S1070363220120439

    Article  CAS  Google Scholar 

  4. Shevchenko, O.V., Plekhova, N.G, Medkov, M.A., Parichuk, K.A., Apanasevich, V.I., Tananaev, I.G., Yudakov, A.A., and Lukyanov, P.A., Russ. J. Inorg. Chem., 2022, vol. 67, no. 9, p. 1361. https://doi.org/10.1134/S003602362209011X

    Article  CAS  Google Scholar 

  5. Kalinovskaya, I.V. and Zadorozhnaya, A.N., Mol. Struct., 2017, vol. 1157, p. 14. https://doi.org/10.1016/j.molstruc.2017.11.035

    Article  CAS  Google Scholar 

  6. Kalinovskaya, I.V., Mol. Struct., 2018, vol. 1173, p. 328. https://doi.org/10.1016/j.molstruc.2018.06.118

    Article  CAS  Google Scholar 

  7. Kataoka, H., Kitano, T., Takizawa, T., Hirai, Y., Nakanishi, T., and Hasegawa, Y., J. Alloys Compd., 2014, vol. 601, p. 293. https://doi.org/10.1016/j.jallcom.2014.01.165

    Article  CAS  Google Scholar 

  8. Hasegawa, Y. and Nakanishi, T., RSC Adv., 2015, vol. 5, p. 338. https://doi.org/10.1039/C4RA09255D

    Article  CAS  Google Scholar 

  9. Carvalho Filho, M.A.S. and Ionashiro, M., Eclet. Quim., 1998, vol. 23, p. 9.

    Google Scholar 

  10. Carvalho Filho, M.A.S., Fernandes, N.S., Leles, M.I.G., Mendes, R., and Ionashiro, M., J. Therm. Anal. Calorim., 2000, vol. 59, p. 669. https://doi.org/10.1023/A:1010181032172

    Article  Google Scholar 

  11. Emelina, T., Zadorozhnaya, A., Kalinovskaya, I., and Mirochnik, A., Spectrochim. Acta A, 2020, vol. 225, ID 117481. https://doi.org/10.1016/j.saa.2019.117481

  12. Kalinovskaya, I.V., Zadorozhnaya, A.N., and Privar, Yu.O., Russ. J. Gen. Chem., 2021, vol. 91, no. 2, p. 196. https://doi.org/10.1134/S1070363221020079

    Article  CAS  Google Scholar 

  13. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York: John Wiley & Sons, 1986.

  14. Misra, S.N. and Singh, M., J. Ind. Chem. Soc., 1983, vol. 60, no. 2, p. 115.

    CAS  Google Scholar 

  15. Pimentel, P.M., Oliveira, V.S., Silva, Z.R., Melo, D.M.A., Zinner, L.B., Vicentini, G., and Bombieri, G., Polyhedron, 2000, vol. 19, p. 2651. https://doi.org/10.1016/S0277-5387(01)00868-3

    Article  Google Scholar 

  16. Bellamy, L.J., The Infra-Red Spectra of Complex Molecules, London: Methuen & Сo. Ltd., 1963.

Download references

Funding

The work was carried out with financial support from the Ministry of Education and Science (state assignment topic number 0265-2014-0001).

Author information

Authors and Affiliations

  1. Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 690022, Vladivostok, Russia

    I. V. Kalinovskaya

  2. Pacific State University of Medicine, 690002, Vladivostok, Russia

    A. N. Zadorozhnaya

  3. Rostov State Transport University, 344038, Rostov-on-Don, Russia

    I. A. Estrin

Authors
  1. I. V. Kalinovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. N. Zadorozhnaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Estrin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. V. Kalinovskaya.

Ethics declarations

The authors declare no conflict of interest.

Additional information

Publisher's Note. Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kalinovskaya, I.V., Zadorozhnaya, A.N. & Estrin, I.A. New Europium Methoxycinnamates: Synthesis and Thermal and Luminescence Properties. Russ J Gen Chem 93, 2542–2548 (2023). https://doi.org/10.1134/S1070363223100092

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363223100092

Keywords:

Search

Navigation