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Synthesis and Physicochemical Properties of Tin(IV), Zirconium(IV), and Hafnium(IV) 2(3),9(10),16(17),23(24)-Tetrakis-(4-tritylphenoxy)phthhalocyaninates

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Abstract

Tetrakis-(4-tritylphenoxy)phthalocyaninates of tin(IV), zirconium(IV), and hafnium(IV) were synthesize by the reactions of 4-tritylphenoxyphthalonitrile with SnCl2, ZrCl4, and HfCl4 catalyzed by ammonium molybdate in the presence of urea. The structures of the complexes were characterized by spectral methods, including mass spectrometry, 1H NMR, vibrational and electronic spectroscopy. The resulting complexes form J-type dimeric associates in chloroform at concentrations up to ~1.5×10–6 M and lower, are not associated in a mixture of toluene and pyridine up to concentrations of ~3×10–5 M and higher, and show catalytic activity in the electroreduction of molecular oxygen. Zirconium and hafnium complexes showed the greatest activity. Tin and zirconium complexes are thermally stable in an inert atmosphere up to 200°C.

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Funding

The work was carried out within the framework of the state task for the implementation of research work (subject no. FZZW-2020-0010) using the equipment of the Center for Collective Use of the Ivanovo State University of Chemistry and Technology with the support of the Ministry of Education and Science of Russia (agreement no. 075-15-2021-671).

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  1. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    T. A. Rumyantseva, M. I. Vazanov & N. E. Galanin

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  1. T. A. Rumyantseva
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  2. M. I. Vazanov
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  3. N. E. Galanin
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Correspondence to N. E. Galanin.

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Rumyantseva, T.A., Vazanov, M.I. & Galanin, N.E. Synthesis and Physicochemical Properties of Tin(IV), Zirconium(IV), and Hafnium(IV) 2(3),9(10),16(17),23(24)-Tetrakis-(4-tritylphenoxy)phthhalocyaninates. Russ J Gen Chem 93, 1760–1766 (2023). https://doi.org/10.1134/S1070363223070174

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