Skip to main content

Synthesis and Extraction Properties of Tripodal Tetraphosphoryl Ligands on the Triphenylphosphine Oxide Platform


New tetraphosphoryl tripodal ligands on the triphenylphosphine oxide platform [2-Ph2P(O)(CH2)nOC6H4]3PO with different linker length (n = 3, 4) were synthesized. Their composition and structure were determined by elemental analysis, IR and multinuclear (1H, 13C, and 31P) NMR spectroscopy, and X-ray diffraction analysis. Extraction properties of the ligands were studied using the example of extraction of microamounts of f-elements from an aqueous phase into 1,2-dichloroethane.

This is a preview of subscription content, access via your institution.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.


  1. Bryleva, Yu.A., Artem’ev, A.V., Glinskaya, L.A., Samsonenko, D.G., Rakhmanova, M.I., Davydova, M.P., and Yzhikova, K.M., J. Struct. Chem., 2021, vol. 62, no. 2, p. 265.

    Article  CAS  Google Scholar 

  2. Bryleva, Y.A., Artem’ev, A.V., Glinskaya, L.A., Rakhmanova, M.I., Samsonenko, D.G., Komarov, V.Yu., Rogovoy, M.I., and Davydova, M.P., New J. Chem., 2021, vol. 45, no. 13, p. 13869.

    Article  CAS  Google Scholar 

  3. Turanov, A.N., Karandashev, V.K., Baulin, D.V., Baulin, V.E., and Tsivadze, A.Yu., Russ. Chem. Bull., 2021, vol. 70, no. 12, p. 2416.

    Article  CAS  Google Scholar 

  4. Chmutova, M.K., Ivanova, L.A., Bodrin, G.B., Polikarpov, Yu.M., and Myasoedov, B.F., Radiokhimiya, 1994, vol. 36, no. 4, p. 320.

    CAS  Google Scholar 

  5. Chmutova, M.K., Matrosov, E.I., Ivanova, L.A., Bodrin, G.V., Myasoedov, B.F., and Kabachnik, M.I., Radiokhimiya, 1993, vol. 35, no. 1, p. 70.

    CAS  Google Scholar 

  6. Lees, A.M.J. and Platt, A.W.G., Polyhedron, 2005, vol. 24, no. 3, p. 427.

    Article  CAS  Google Scholar 

  7. Deb, B., Sarmah, B.J., Borah, B.J., and Dutta, D.K., Spectrochim. Acta A, 2009, vol. 72, no. 2, p. 339.

    Article  CAS  Google Scholar 

  8. Pisareva, S.A., Petrovskii, P.V., Lyssenko, K.A., Antipin, M.Yu., and Nifant’ev, E.E., Russ. Chem. Bull., 2004, vol. 53, no. 9, p. 2008.

    Article  CAS  Google Scholar 

  9. Reinoso-Garcıa, M.M., Janczewski, D., Reinhoudt, D.N., Verboom, W., Malinowska, E., Pietrzak, M., Hill, C., Baca, J., Gruner, B., Seluckye, P., and Gruttner, C., New J. Chem., 2006, vol. 30, no. 10, p. 1480.

    Article  CAS  Google Scholar 

  10. Sharova, E.V., Artyushin, O.I., Turanov, A.N., Karandashev, V.K., Meshkova, S.B., Topilova, Z.M., and Odinets, I.L., Cent. Eur. J. Chem., 2012, vol. 10, no. 1, p. 146.

    Article  CAS  Google Scholar 

  11. Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Radiochemistry, 2002, vol. 44, no. 1, p. 26.

    Article  CAS  Google Scholar 

  12. Turanov, A.N., Karandashev, V.K., Baulin, V.E., and Tsivadze, A.Yu., Russ. J. Inorg. Chem., 2014, vol. 59, no. 8, p. 891.

    Article  CAS  Google Scholar 

  13. Gusarova, N.K., Kuimov, V.A., Malysheva, S.F., Belogorlova, N.A., Albanov, A.I., and Trofimov, B.A., Tetrahedron, 2012, vol. 68, no. 45, p. 9218.

    Article  CAS  Google Scholar 

  14. Matveeva, A.G., Kudryavtsev, I.Yu., Pasechnik, M.P., Vologzhanina, A.V., Baulina, T.V., Vavina, A.V., Sukat, G.Ya., Matveev, S.V., Godovikov, I.A., Turanov, A.N., Karandashev, V.K., and Brel, V.K., Polyhedron, 2018, vol. 142, p. 71.

    Article  CAS  Google Scholar 

  15. Kudryavtsev, I.Y., Bykhovskaya, O.V., Matveeva, A.G., Baulina, T.V., Pasechnik, M.P., Matveev, S.V., Vologzhanina, A.V., Turanov, A.N., Karandashev, V.K., and Brel, V.K., Monatsh. Chem., 2020, vol. 151, no. 11, p. 1705.

    Article  CAS  Google Scholar 

  16. Bykhovskaya, O.V., Matveeva, A.G., Pasechnik, M.P., Vologzhanina, A.V., Matveev, S.V., Kudryavtsev, I.Yu., Baulina, T.V., and Brel, V.K., Russ. J. Gen. Chem., 2019, vol. 89, no. 12, p. 2400.

    Article  CAS  Google Scholar 

  17. Matveeva, A.G., Bykhovskaya, O.V., Pasechnik, M.P., Vologzhanina, A.V., Aysin, R.R., Matveev, S.V., Godovikov, I.A., Kudryavtsev, I.Y., Baulina, T.V., and Brel, V.K., Mendeleev Commun., 2022, vol. 32, no. 5, p. 588.

    Article  CAS  Google Scholar 

  18. Armarego, W.L.F. and Chai, C.L.L., Purification of Laboratory Chemicals, New York: Elsevier, 2009.

  19. Tsvetkov, E.N., Bondarenko, N.A., Malakhova, I.G., and Kabachnik, M.I., Synthesis, 1986, no. 3, p. 198.

    Article  Google Scholar 

  20. Kudryavtsev, I.Yu., Baulina, T.V., Khrustalev, V.N., Petrovskii, P.V., Pasechnik, M.P., and Nifant’ev, E.E., Doklady Chem., 2013, vol. 448, no. 2, p. 55.

    Article  CAS  Google Scholar 

  21. Gel’man, N.E., Terent’eva, E.A., Shanina, T.M., and Kiparenko, L.M., Metody kolichestvennogo organicheskogo elementnogo mikroanaliza (Methods of Quantitative Organic Elemental Microanalysis), Moscow: Khimiya, 1987.

  22. Ragulin, V.V., Russ. J. Gen. Chem., 2012, vol. 82, no. 12, p. 1928.

    Article  CAS  Google Scholar 

  23. SADABS. BrukerAXS Inc., Madison, Wisconsin, USA.

  24. Sheldrick, G.M., Acta Crystalogr. A, 2015, vol. 71, no. 1, p. 3.

    Article  CAS  Google Scholar 

  25. Sheldrick, G.M., Acta Crystallogr. C, 2015, vol. 71, no. 1, p. 3.

    Article  CAS  Google Scholar 

  26. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystalogr., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  27. Matveeva, A.G., Baulina, T.V., Kudryavtsev, I.Yu., Pasechnik, M.P., Aysin, R.R., Bykhovskaya, O.V., Godovikova, M.I., Matveev, S.V., Turanov, A.N., Karandashev, V.K., and Brel, V.K., Russ. J. Gen. Chem., 2020, vol. 90, no. 12, p. 2338.

    Article  CAS  Google Scholar 

Download references


The work was carried out within the framework of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (no. 075-03-2023-642).

Author information

Authors and Affiliations


Corresponding author

Correspondence to T. V. Baulina.

Ethics declarations

The authors declare that there is no conflict of interest.

Rights and permissions

Reprints and Permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baulina, T.V., Kudryavtsev, I.Y., Pasechnik, M.P. et al. Synthesis and Extraction Properties of Tripodal Tetraphosphoryl Ligands on the Triphenylphosphine Oxide Platform. Russ J Gen Chem 93, 1703–1710 (2023).

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: