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Synthesis and Extraction Properties of Tripodal Tetraphosphoryl Ligands on the Triphenylphosphine Oxide Platform

Russian Journal of General Chemistry volume 93, pages 1703–1710 (2023)Cite this article

Abstract

New tetraphosphoryl tripodal ligands on the triphenylphosphine oxide platform [2-Ph2P(O)(CH2)nOC6H4]3PO with different linker length (n = 3, 4) were synthesized. Their composition and structure were determined by elemental analysis, IR and multinuclear (1H, 13C, and 31P) NMR spectroscopy, and X-ray diffraction analysis. Extraction properties of the ligands were studied using the example of extraction of microamounts of f-elements from an aqueous phase into 1,2-dichloroethane.

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Funding

The work was carried out within the framework of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (no. 075-03-2023-642).

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Moscow, Russia

    T. V. Baulina, I. Yu. Kudryavtsev, M. P. Pasechnik, A. G. Matveeva, S. V. Matveev, A. V. Vologzhanina & V. K. Brel

  2. Institute of Solid-State Physics of the Russian Academy of Sciences, 142432, Chernogolovka, Russia

    A. N. Turanov

  3. Institute of Microelectronics Technology and High Purity Materials of the Russian Academy of Sciences, 142432, Chernogolovka, Russia

    V. K. Karandashev

  4. National University of Science and Technology MISiS, 119991, Moscow, Russia

    V. K. Karandashev

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  1. T. V. Baulina
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  2. I. Yu. Kudryavtsev
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  3. M. P. Pasechnik
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  4. A. G. Matveeva
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  5. S. V. Matveev
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  6. A. V. Vologzhanina
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  7. A. N. Turanov
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  8. V. K. Karandashev
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  9. V. K. Brel
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Correspondence to T. V. Baulina.

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Baulina, T.V., Kudryavtsev, I.Y., Pasechnik, M.P. et al. Synthesis and Extraction Properties of Tripodal Tetraphosphoryl Ligands on the Triphenylphosphine Oxide Platform. Russ J Gen Chem 93, 1703–1710 (2023). https://doi.org/10.1134/S1070363223070101

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