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Features of the Rheological Behavior of Starch Hydrogels Modified with Synthetic Latexes

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

The rheological properties of starch-latex blends mechanically activated in a rotary-pulse apparatus were studied. Several integral criteria—flexibility, polarity and hydrophilicity of macromolecules, particle size and electrokinetic potential—were chosen to evaluate the effectiveness of starch modification with synthetic copolymer latexes. An increase in the blends viscosity was shown to observe for more flexible polymers Binder RA, Binder AF, Ruzin with a glass transition temperature (Tg) below 25°C. Polymers BAK-R and Aquapol with high values of the modulus E′ reduce viscosity. The hydrophilicity of synthetic copolymers and their particle size promote an increase in the blends viscosity.

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Funding

The work was carried out under government contracts (study of modifiers (Subject No. FZZW-2023-0009), study of rheology (Subject No. 01201260484)). The size and electrokinetic potential were determined using the equipment of the Center for Collective Use “Upper Volga Regional Center for Physical and Chemical Research.” Dynamic mechanical analysis was performed using the resources of the Center for the Collective Use of Scientific Equipment of the ISUCT (with the support of the Russian Ministry of Education and Science, agreement no. 075-15-2021-671).

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Authors and Affiliations

  1. Department of Chemistry and Technology of Macromolecular Compounds, Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    I. P. Trifonova, V. A. Burmistrov, J. A. Rodicheva & O. I. Koifman

  2. G.A. Krestov Institute of Solution Chemistry of Russian Academy of Sciences, 153045, Ivanovo, Russia

    N. V. Losev & I. M. Lipatova

Authors
  1. I. P. Trifonova
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  2. V. A. Burmistrov
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  3. N. V. Losev
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  4. J. A. Rodicheva
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  5. I. M. Lipatova
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  6. O. I. Koifman
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Corresponding authors

Correspondence to I. P. Trifonova or I. M. Lipatova.

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Trifonova, I.P., Burmistrov, V.A., Losev, N.V. et al. Features of the Rheological Behavior of Starch Hydrogels Modified with Synthetic Latexes. Russ J Gen Chem 93, 1591–1598 (2023). https://doi.org/10.1134/S1070363223060336

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