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Synthesis, Structures, and Magnetic Properties of Two 1D Mn(II)/Co(II)-Coordination Polymers with Triazolyl Derivatives and Terephthalic Acid

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Abstract

Two isomorphic one-dimensional coordination polymers, [Mn(tp)0.5(HL)(H2O)]n·nH2O and [Co(tp)0.5(HL)(H2O)]n·nH2O [H2L = 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole; H2tp = terephthalic acid], were synthesized under hydrothermal conditions. The title compounds were characterized by single-crystal and powder X-ray diffractions, FTIR, and TGA. Both compounds crystallize in triclinic, space group P-1. They display a one-dimensional chain structure, those are connected by O–H···O hydrogen bonds to generate 2D structure. In addition, temperature-dependent magnetic susceptibility studies for the complexes were described. The results indicate that domain a weak antiferromagnetic exchange coupling between the adjacent Mn(II) centers in [Mn(tp)0.5(HL)(H2O)]n·nH2O , and the magnetic susceptibility from 60 to 300 K obeys the Curie–Weiss law with a Weiss constant θ of –11.84 K in [Co(tp)0.5(HL)(H2O)]n·nH2O.

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Funding

This work was financially supported by the Institutions of higher learning key scientific research project of Henan Province (21A413001) and the Program for Science & Technology Innovation Talents in Universities of Henan Province (no. 21IRTSTHN004).

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Authors and Affiliations

  1. College of Food and Drug, Luoyang Normal University, 471934, Luoyang, China

    C. J. He

  2. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, 471934, Luoyang, China

    Y. F. Wang & S. H. Li

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  1. C. J. He
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  2. Y. F. Wang
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Correspondence to Y. F. Wang.

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He, C.J., Wang, Y.F. & Li, S.H. Synthesis, Structures, and Magnetic Properties of Two 1D Mn(II)/Co(II)-Coordination Polymers with Triazolyl Derivatives and Terephthalic Acid. Russ J Gen Chem 93, 1004–1010 (2023). https://doi.org/10.1134/S1070363223040308

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