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Composite Films Based on Polyacrylonitrile and Detonation Nanodiamonds

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Abstract

The properties of composite films based on polyacrylonitrile and detonation nanodiamonds were studied. It was found that the surface properties of the films (roughness and specific free surface energy) do not change when nanodiamonds are added. It was shown by autoradiography technique with tritium-labeled nanodiamonds that the distribution of particles in a film depends on the modification of their surface. Additives of particles and heat treatment affect the mechanical behavior of the films, and the samples become more brittle. Modification of the nanodiamonds with perfluorononanoic acid leads to a decrease in the strength of the films.

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Funding

The work was carried out with the financial support of the state program “Colloidal chemistry as the basis for the creation of promising materials and nanostructured systems with controlled properties” (no. 121031300084-1). Thermogravimetric analysis was performed on equipment obtained under the Development Program of the Lomonosov Moscow State University.

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  1. M.V. Lomonosov Moscow State University, 119991, Moscow, Russia

    O. A. Soboleva & E. V. Porodenko

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  1. O. A. Soboleva
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  2. E. V. Porodenko
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Correspondence to O. A. Soboleva.

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Soboleva, O.A., Porodenko, E.V. Composite Films Based on Polyacrylonitrile and Detonation Nanodiamonds. Russ J Gen Chem 93, 892–899 (2023). https://doi.org/10.1134/S1070363223040163

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  • DOI: https://doi.org/10.1134/S1070363223040163

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