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Preparation, Thermal Properties, and Electrical Conductivity of Solutions of Pyridinium Ionic Liquids with Tetrachloroferrate Anion

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Abstract

Thermal stability of N-alkylpyridinium tetrachloroferrates(III) [C5H5NR]FeCl4 [R = C4H9, (CH2)3CN, CH2C6H5, C8H17, and C10H21] in air in the range of 25–600°C has been studied, as well as the thermal stability of N-alkylpyridinium chlorides. The equivalent electrical conductivity of N-alkylpyridinium tetrachloroferrates(III) in acetonitrile solution at 25°C has been investigated. The ionic association constants Ka, the limiting molar electrical conductivity (λ0), and the standard Gibbs energy of the association (ΔG°) in the acetonitrile solutions have been calculated based on conductometric data via the Lee–Wheaton method.

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Authors and Affiliations

  1. Tver State University, 170002, Tver, Russia

    O. E. Zhuravlev, A. D. Kaftanov & G. S. Yulmasov

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  1. O. E. Zhuravlev
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  2. A. D. Kaftanov
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Zhuravlev, O.E., Kaftanov, A.D. & Yulmasov, G.S. Preparation, Thermal Properties, and Electrical Conductivity of Solutions of Pyridinium Ionic Liquids with Tetrachloroferrate Anion. Russ J Gen Chem 93, 855–862 (2023). https://doi.org/10.1134/S1070363223040114

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