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Synthesis and Extraction Properties of 4,5-Diphosphorylated Triazoles

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Abstract

A method for the synthesis of 4,5-diphosphorylated 1,2,3-triazoles has been developed and their extraction properties with respect to U(VI), Th(IV), and lanthanide(III) ions have been studied. A synergistic effect was found in the extraction of metal ions with mixtures of 4,5-diphosphorylated 1,2,3-triazoles and dinonylnaphthalenesulfonic acid. The stoichiometry of the extracted complexes was determined, and the influence of the extractant structure and the HNO3 concentration in the aqueous phase on the efficiency of the metal ions extraction into the organic phase was considered. It was found that 4,5-diphosphorylated 1,2,3-triazole with the octyl substituent at nitrogen atom has the highest extraction ability with respect to actinides and lanthanides in nitric acid media.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation (INEOS RAS Contract no. 075-03-2023-642) using the scientific equipment of the Center for Research on the Structure of Molecules of the A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Yu.A. Ossipyan Institute of Solid State Physics of the Russian Academy of Sciences, 142432, Chernogolovka, Russia

    A. N. Turanov

  2. Institute of Microelectronics Technology and High Pure Materials of the Russian Academy of Sciences, 142432, Chernogolovka, Russia

    V. K. Karandashev

  3. A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Moscow, Russia

    O. I. Artyushin, E. V. Smirnova & V. K. Brel

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  1. A. N. Turanov
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  2. V. K. Karandashev
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Correspondence to E. V. Smirnova.

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Turanov, A.N., Karandashev, V.K., Artyushin, O.I. et al. Synthesis and Extraction Properties of 4,5-Diphosphorylated Triazoles. Russ J Gen Chem 93, 841–848 (2023). https://doi.org/10.1134/S1070363223040096

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