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Synthesis, Structure, and Property of Noncentrosymmetrical Coordination Polymer Based on Mixed Functional Ligands and Zinc Ions

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Abstract

One 3d-metal coordination polymer [Zn(Hspas)(Hpco)(H2O)]n (1) (NaH2spas = 5-sulfoisophthalic acid monosodium salt, Hpco = 2-pyridinecarbaldehyde oxime), was synthesized by solvent evaporation method under magnetci field. Each Zn atom is hexcoordinated with a distorted octahedral arrangement. Each Hspas2– anion acts as a tridentate ligand, which bridges with three Zn ions to form a two-dimensional layered structure. The two-dimensional structures are further linked by hydrogen bonds to generate a three-dimensional supramolecular structure. Complex 1 exhibits the photoluminescent emission with maximum at 396 nm, which arises from the ligand centered π–π*-transitions. The emission intensity of complex 1 is higher than that of NaH2spas ligand, which is indicative of the influence of the d10 closed shell electronic configuration of zinc ion on fluorescence property. In addition, complex 1 has the response of second-harmonic-generation (SHG) with 2 times that of KH2PO4.

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Funding

This work was supported by Basic Scientific Research Project of Universities from Liaoning Provincial Education Department (grant no. LJKZ0371 and LJKMZ20220738) and Innovation and Entrepreneurship Training Program for University Students (grant no. X202210148024).

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Authors and Affiliations

  1. School of Petrochemical Engineering, Liaoning Petrochemical University, 113001, Fushun, China

    Ying Wang, Xiangze Ren, Lei Guan & Xuejia Xiong

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  1. Ying Wang
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  2. Xiangze Ren
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  3. Lei Guan
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  4. Xuejia Xiong
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Correspondence to Lei Guan.

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Wang, Y., Ren, X., Guan, L. et al. Synthesis, Structure, and Property of Noncentrosymmetrical Coordination Polymer Based on Mixed Functional Ligands and Zinc Ions. Russ J Gen Chem 93, 628–634 (2023). https://doi.org/10.1134/S1070363223030192

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