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Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)

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Abstract

The published data of various methods on the structural characteristics of the nearest environment of some monatomic inorganic cations in aqueous solutions and in acetonitrile under standard conditions are summarized. The structures of the first solvation shells of cations in these solvents have been compared quantitatively. It is suggested that for these systems, the structure of solvation shells of cations are independent of the solvent, and is determined only by the physicochemical nature of the ions.

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The study was carried out with the financial support of the Russian foundation for basic research and Ivanovo oblast as part of scientific project no. 20-43-370001.

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  1. G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045, Ivanovo, Russia

    P. R. Smirnov

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Smirnov, P.R. Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review). Russ J Gen Chem 93, 575–585 (2023). https://doi.org/10.1134/S1070363223030143

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