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“2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate

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Abstract

“2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.

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Funding

The study was financially supported by the Russian Science Foundation (project no. 22-13-00057).

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Authors and Affiliations

  1. Khlopin Radium Institute, 194021, St. Petersburg, Russia

    A. E. Miroslavov, A. P. Sakhonenkova, M. Yu. Tyupina & G. V. Sidorenko

  2. St. Petersburg State University, 199034, St. Petersburg, Russia

    A. E. Miroslavov & A. P. Sakhonenkova

  3. Ozersk Institute of Technology, Branch of National Research Nuclear University Moscow Engineering Physics Institute, Chelyabinsk oblast, 456783, Ozersk, Russia

    A. E. Miroslavov, A. P. Sakhonenkova & M. Yu. Tyupina

  4. St. Petersburg State Pediatric Medical University, 194100, St. Petersburg, Russia

    M. Yu. Tyupina

Authors
  1. A. E. Miroslavov
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  2. A. P. Sakhonenkova
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  3. M. Yu. Tyupina
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  4. G. V. Sidorenko
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Correspondence to M. Yu. Tyupina.

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Miroslavov, A.E., Sakhonenkova, A.P., Tyupina, M.Y. et al. “2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate. Russ J Gen Chem 93, 327–331 (2023). https://doi.org/10.1134/S1070363223020135

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  • DOI: https://doi.org/10.1134/S1070363223020135

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