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Complex of Mn(II) Perchlorate with (2-Methylenepropane-1,3-diyl)bis(diphenylphosphine Oxide): Synthesis, Structure, and Double Luminescence

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Abstract

The previously unknown complex [MnL2(MeOH)2](ClO4)2 was synthesized in the methanol–dichloromethane system by the reaction of Mn(ClO4)2·6H2O with (2-methylenepropan-1,3-diyl)bis(diphenylphosphine oxide) (L). According to X-ray diffraction data, its Mn2+ ion has a distorted octahedral environment Mn@O6 formed by two chelate ligands L and two coordinated methanol molecules. At 298 K, this complex exhibits low-intensity double luminescence, the low-energy component of which is attributed to Mn2+-centered phosphorescence, and the high-energy component - to intraligand fluorescence.

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Funding

The synthesis of the initial ligand and the complex was carried out within the framework of the state task (no. 075-00697-22-00). X-ray structural and spectral studies were carried out with the support of the Ministry of Science and Higher Education of the Russian Federation (projects nos. 121031700321-3, 121031700313-8, and 1021051503141-0-1.4.1).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. P. Davydova & M. I. Rakhmanova

  2. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    I. Yu. Bagryanskaya

  3. A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119334, Moscow, Russia

    V. K. Brel

Authors
  1. M. P. Davydova
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  2. I. Yu. Bagryanskaya
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  3. M. I. Rakhmanova
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  4. V. K. Brel
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Corresponding author

Correspondence to V. K. Brel.

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Davydova, M.P., Bagryanskaya, I.Y., Rakhmanova, M.I. et al. Complex of Mn(II) Perchlorate with (2-Methylenepropane-1,3-diyl)bis(diphenylphosphine Oxide): Synthesis, Structure, and Double Luminescence. Russ J Gen Chem 93, 321–326 (2023). https://doi.org/10.1134/S1070363223020123

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