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New Reactions of Acetylene Generated in Two-Chamber Reactor

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Abstract

For the first time reactions of acetylene generated in a two-chamber reactor with methyl diazoacetate, iodine and benzoyl chlorides were studied. Methyl 1H-pyrazole-3-carboxylate, (E)-1,2-diiodoethylene, (E)-1,2-dideutero-1,2-diiodoethylene, (2E)-1-aryl-3-chloroprop-2-en-1-ones, including D-labeled 3-chloro-2,3-dideutero-1-phenylprop-2-en-1-one were synthesized.

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ACKNOWLEDGMENTS

The authors thank the Resource Centers of St. Petersburg State University “Magnetic Resonance Research Centre” and “Chemical Analysis and Materials Research Centre.”

Funding

This work was financially supported by the Council for Grants under the President of the Russian Federation (project no. MK-2615.2021.1.3) and St. Petersburg State University (PURE ID 92285019, V.V. Voronin).

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Authors and Affiliations

  1. St. Petersburg State University, 199034, St. Petersburg, Russia

    M. S. Ledovskaya, V. V. Voronin & N. R. Valov

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  1. M. S. Ledovskaya
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  2. V. V. Voronin
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  3. N. R. Valov
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Correspondence to M. S. Ledovskaya.

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Ledovskaya, M.S., Voronin, V.V. & Valov, N.R. New Reactions of Acetylene Generated in Two-Chamber Reactor. Russ J Gen Chem 93, 235–239 (2023). https://doi.org/10.1134/S1070363223020019

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