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Effect of Alkaline Activation on the Structural Characteristics of Nanocomposites Based on Carbonized Chitosan and Fe–Co Bimetallic Nanoparticles

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Abstract

Metal-carbon nanocomposites consisting of Fe–Co bimetallic nanoparticles uniformly dispersed in the carbon matrix were synthesized by pyrolysis of a precursor based on chitosan and metal salts in the temperature range 500–800°C. The change in the structural characteristics of the samples after activation in the presence of potassium hydroxide was studied. It was found that alkaline activation leads to an increase in the specific surface area of the nanocomposites up to 700 m2/g and in the size of metal nanoparticles, whereas the phase composition and morphology of the carbon support remain unchanged.

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Funding

This work was carried out within the State Program of TIPS RAS. This study was performed using the equipment of the Shared Research Center “Analytical center of deep oil processing and petrochemistry of TIPS RAS,” “New Petrochemical Processes, Polymer Composites and Adhesives” and the NRC “Kurchatov Institute” – IREA.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis RAS, 119991, Moscow, Russia

    A. A. Vasilev, M. N. Efimov, D. G. Muratov & G. P. Karpacheva

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  1. A. A. Vasilev
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  2. M. N. Efimov
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  3. D. G. Muratov
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  4. G. P. Karpacheva
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Correspondence to A. A. Vasilev.

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Vasilev, A.A., Efimov, M.N., Muratov, D.G. et al. Effect of Alkaline Activation on the Structural Characteristics of Nanocomposites Based on Carbonized Chitosan and Fe–Co Bimetallic Nanoparticles. Russ J Gen Chem 93, 74–84 (2023). https://doi.org/10.1134/S1070363223010115

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