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Synthesis and Extraction Properties of 2-(3,4-Diphenylphosphinylpyrrolidin-1-yl)ethanol and 3-(3,4-Diphenylphosphinylpyrrolidin-1-yl)propanol

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Abstract

A method for the synthesis of 2-(3,4-diphenylphosphinylpyrrolidin-1-yl)ethanol and 3-(3,4-diphenylphosphinylpyrrolidin-1-yl)propanol was developed, and extraction of U(VI), Th(IV), and lanthanides(III) from nitric acid solutions was studied. The stoichiometry of the extracted complexes was determined, and the influence of the extractant structure and the HNO3concentration in the aqueous phase on the efficiency of extraction of the metal ions into the organic phase was evaluated. It was found that 2-(3,4-diphenylphosphinylpyrrolidin-1-yl)ethanol exhibits high extraction ability with respect to actinides and lanthanides in nitrate media.

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Funding

This study was financially supported in the framework of the State Task for the Osip’yan Institute of Solid State Physics, Russian Academy of Sciences, Institute of Microelectronics Technology and High-Purity Materials, Russian Academy of Sciences, and Nesmeaynov Institute of Organoelement Compounds, Russian Academy of Sciences, for the year 2022. Synthesis of the compounds was supported by the Russian Science Foundation (project no. 20-13-00329). Registration of the NMR spectra was carried out under financial support from the Ministry of Science and Higher Education of the Russian Federation with the use of scientific equipment of the Center for Molecular Structure Studies, Institute of Organoelement Compounds, Russian Academy of Sciences.

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Authors and Affiliations

  1. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    A. N. Turanov

  2. Institute of Microelectronics Technology and High-Purity Materials, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    V. K. Karandashev

  3. Nesmeaynov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    V. K. Brel

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  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. V. K. Brel
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Correspondence to V. K. Brel.

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V.K. Brel, a co-author, is an Editorial Board member at Zhurnal Obshchei Khimii (Journal of General Chemistry). The other co-authors declare no conflict of interest.

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Turanov, A.N., Karandashev, V.K. & Brel, V.K. Synthesis and Extraction Properties of 2-(3,4-Diphenylphosphinylpyrrolidin-1-yl)ethanol and 3-(3,4-Diphenylphosphinylpyrrolidin-1-yl)propanol. Russ J Gen Chem 92, 2647–2652 (2022). https://doi.org/10.1134/S1070363222120131

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