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Photochemical Synthesis and Catalytic Properties of Materials Containing Cerium(IV) Oxide and Gold Nanoparticles

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Abstract

Gold nanoparticles on the surface of cerium(IV) oxide were obtained by photochemical reduction of HAuCl4 in water–alcohol solutions. The spectral characteristics of the resultant nanocomposites, their phase composition and morphology, and the kinetics of the gold particles formation were examined depending on the nature of the monohydric alcohol and on the morphology of the cerium(IV) oxide particles. The catalytic activity of cerium(IV) oxide before and after modification with gold nanoparticles in the reactions of photodegradation of methyl orange and phenol was studied. It was shown that the CeO2 particles modified with gold nanoparticles upon irradiation with UV light have the highest photocatalytic activity.

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ACKNOWLEDGMENTS

Physicochemical studies were carried out using the equipment of the Center for Collective Use, Department of Chemistry, Gertsen Russian State Pedagogical University, as well as of the equipment of the Composition, Structure, and Properties of Structural and Functional Materials, Center for Collective Use of Scientific Equipment, Gorynin Central Research Institute of Structural Materials “Prometei,” National Research Center “Kurchatov Institute”.

Funding

This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation [project no. 13.TsKP.21.0014 (075-11-2021-068), unique identifier RF 2296.61321X0014].

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, 191186, St. Petersburg, Russia

    E. I. Isaeva, N. V. Gur’ev, T. B. Boitsova & V. P. Pronin

  2. Gorynin Central Research Institute of Structural Materials “Prometei”, National Research Center “Kurchatov Institute”, 191015, St. Petersburg, Russia

    M. V. Staritsyn & M. L. Fedoseev

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  1. E. I. Isaeva
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  2. N. V. Gur’ev
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Correspondence to E. I. Isaeva.

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Isaeva, E.I., Gur’ev, N.V., Boitsova, T.B. et al. Photochemical Synthesis and Catalytic Properties of Materials Containing Cerium(IV) Oxide and Gold Nanoparticles. Russ J Gen Chem 92, 1972–1982 (2022). https://doi.org/10.1134/S1070363222100115

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