Skip to main content
Log in

Synthesis of Silver Nanoplates by the Polyol Method in the Presence of an Ethoxylated Carboxylic Acid and Glucose

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Triangular and hexagonal silver nanoplates were synthesized by the reduction of silver(I) nitrate in ethylene glycol in the presence of 2-[2-(2-methoxyethoxy)ethoxy]acetic acid sodium salt and glucose. The resulting particles were characterized by X-ray phase analysis and electron microscopy. The presence of glucose and NaOH in the reaction mixture allows lowering the synthesis temperature to 30°C, increasing the yield of the nanoplates to 70%, and decreasing their thickness to 25 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme
Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Kamyshny, A., Steinke, J., and Magdassi, S., Open Appl. Phys. J., 2010, vol. 4, p. 19. https://doi.org/10.2174/1874183501104010019

    Article  CAS  Google Scholar 

  2. Espera, A.H.Jr., Dizon, J.R.C., Chen, Q., and Advincula, R.C., Prog. Addit. Manuf., 2019, vol. 4, no. 3, p. 245. https://doi.org/10.1007/s40964-019-00077-7

    Article  Google Scholar 

  3. Titkov, A.I., Bulina, N.V., Ulihin, A.S., Shundrina, I.K., Karpova, E.V., Gerasimov, E.Yu., Yukhin, Yu.M., and Lyakhov, N.Z., J. Mater. Sci., 2017, vol. 28, no. 2, p. 2029. https://doi.org/10.1007/s10854-016-5762-0

    Article  CAS  Google Scholar 

  4. Titkov, A.I., Shundrina, I.K., Gadirov, R.M., Odod, A.V., Kurtsevich, A.E., Yukhin, Yu.M., and Lyakhov, N.Z., Mater. Today: Proc., 2018, vol. 5, issue 8, part 2, p. 16042. https://doi.org/10.1016/j.matpr.2018.05.049

    Article  CAS  Google Scholar 

  5. Abhinav, V.K., Rao, V.K.R., Karthik, P.S., and Singh, S.P., RSC Adv., 2015, no. 5, p. 63985. https://doi.org/10.1039/C5RA08205F

    Article  CAS  Google Scholar 

  6. Ren, H.M., Guo, Y., Huang, S.Y., Zhang, K., Yuen, M.M.F., Fu, X.Z., Yu, S., Sun, R., and Wong, C.P., ACS Appl. Mater. Interfaces, 2015, vol. 7, p. 13685. https://doi.org/10.1021/acsami.5b03571

    Article  CAS  PubMed  Google Scholar 

  7. Lee, Y.I., Kim, S., Jung, S.B., Myung, N.V., and Choa, Y.H., ACS Appl. Mater. Interfaces, 2013, vol. 5, no. 13, p. 5908. https://doi.org/10.1021/am401757y

    Article  CAS  PubMed  Google Scholar 

  8. Xue, C. and Mirkin, C.A., Angew. Chem., Int. Ed., 2007, vol. 46, p. 2036. https://doi.org/10.1002/anie.200604637

    Article  CAS  Google Scholar 

  9. Tang, Z., Zhang, Q., Yin, Y., and Chang, C.A., J. Phys. Chem., C, 2014, vol. 118, p. 21589. https://doi.org/10.1021/jp503319s

    Article  CAS  Google Scholar 

  10. Zhang, Q., Li, N., Goebl, J., Lu, Z., and Yin, Y., J. Am. Chem. Soc., 2011, vol. 133, p. 18931. https://doi.org/10.1021/ja2080345

    Article  CAS  PubMed  Google Scholar 

  11. You, T., Sun, S., Song, X., and Xu, S., Cryst. Res. Technol., 2009, vol. 44, no. 8, p. 857. https://doi.org/10.1002/crat.200900332

    Article  CAS  Google Scholar 

  12. Xiong, Y., Siekkinen, A.R., Wang, J., Yin, Y., Kim, M.J., and Xia, Y., J. Mater. Chem., 2007, vol. 17, p. 2600. https://doi.org/10.1039/b705253g

    Article  CAS  Google Scholar 

  13. Titkov, A.I., Logutenko, O.A., Vorob’yov, A.M., Gerasimov, E.Yu., Bulina, N.V., Yukhin, Yu.M., and Lyakhov, N.Z., Russ. J. Gen. Chem., 2019, vol. 89, no. 1, p. 100. https://doi.org/10.1134/S1070363219010183

    Article  CAS  Google Scholar 

  14. Titkov, A.I., Logutenko, O.A., Gerasimov, E.Yu., Shundrina, I.K., Karpova, E.V., and Lyakhov, N.Z., J. Incl. Phenom. Macrocycl. Chem., 2019, vol. 94, nos. 3–4, p. 287. https://doi.org/10.1007/s10847-019-00921-x

    Article  CAS  Google Scholar 

  15. Titkov, A.I., Borisenko, T.A., and Logutenko, O.A., Khim. Interes. Ustoich. Razv., 2020, vol. 28, p. 66. https://doi.org/10.15372/KhUR2020204

    Article  CAS  Google Scholar 

  16. Fievert, F., Lagier, J.P., and Figlarz, M., MRS Bull., 1989, vol. 14, no. 12, p. 29. https://doi.org/10.1557/S0883769400060930

    Article  Google Scholar 

  17. Sun, Y. and Xia, Y., Science, 2002, vol. 298, p. 2176. https://doi.org/10.1126/science.1077229

    Article  CAS  PubMed  Google Scholar 

  18. Titkov, A.I., Gerasimov, E.Yu., Shashkov, M.V., Logutenko, O.A., Bulina, N.V., Yukhin, Yu.M., and Lyakhov, N.Z., Colloid J., 2016, vol. 78, no. 4, p. 515. https://doi.org/10.1134/S1061933X16040189

    Article  CAS  Google Scholar 

  19. Gomes, J.F., Garcia, A.C., Ferreira, E.B., Pires, C., Oliveira, V.L., Tremiliosi-Filho, G., and Gasparotto, L.H.S., Phys. Chem. Chem. Phys., 2015, vol. 17, p. 21683. https://doi.org/10.1039/C5CP02155C

    Article  CAS  PubMed  Google Scholar 

  20. Giersig, M., Ung, T., Liz-Marzan, L.M., and Mulvaney, P., Adv. Mater., 1997, vol. 9, no. 7, p. 570. https://doi.org/10.1002/adma.19970090712

    Article  CAS  Google Scholar 

  21. Shenoy, U.S. and Shetty, A.N., Appl. Nanosci., 2014, vol. 4, p. 47. https://doi.org/10.1007/s13204-012-0169-6

    Article  CAS  Google Scholar 

  22. Pasta, M., Ruffo, R., Falletta, E., Mari, C.M., and Pina, C.D., Gold Bull., 2010, vol. 43, no. 1, p. 57. https://doi.org/10.1007/BF03214967

    Article  CAS  Google Scholar 

  23. Raveendran, P., Fu, J., and Wallen, S.L., Green Chem., 2006, vol. 8, p. 34. https://doi.org/10.1039/B512540E

    Article  CAS  Google Scholar 

  24. Philip, D., Spectrochim. Acta, Part A, 2010, vol. 75, p. 1078. https://doi.org/10.1016/j.saa.2009.12.058

    Article  CAS  Google Scholar 

  25. Wang, H., Qiao, X., Chen, J., and Ding, S., Colloids Surf., A, 2005, vol. 256, nos. 2–3, p. 111. https://doi.org/10.1016/j.colsurfa.2004.12.058

    Article  CAS  Google Scholar 

Download references

Funding

This study was carried out within the framework of the State Assignment to the Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences (project no. 0237-2019-0002).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to O. A. Logutenko.

Ethics declarations

No conflict of interest was declared by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Borisenko, T.A., Logutenko, O.A. & Titkov, A.I. Synthesis of Silver Nanoplates by the Polyol Method in the Presence of an Ethoxylated Carboxylic Acid and Glucose. Russ J Gen Chem 92, 1062–1069 (2022). https://doi.org/10.1134/S1070363222060184

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363222060184

Keywords:

Navigation