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Extraction of REE(III), U(VI), and Th(IV) with Modified Carbamoylmethylphosphine Oxides from Nitric Acid Solutions

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Abstract

Modified extractants, carbamoylmethylphosphine oxides Ph2P(O)CH2CON(R)CH2P(O)Ph2 (R = Et, i-Pr, Bu, Oct), containing a phosphoryl group in the amide part of the molecule, have been synthesized. The extraction of microquantities of REE(III), U(VI), and Th(IV) with solutions of the obtained extractants in organic solvents from nitric acid solutions has been studied. The stoichiometry of the extractable complexes was determined, and the influence of the extractant structure, the organic diluent nature, and the aqueous phase composition on the efficiency and selectivity of the U(VI), Th(IV), and REE(III) extraction into the organic phase was considered. It has been shown that the modification of diphenyl(N,N-dialkylcarbamoylmethyl)phosphine oxide by introducing an additional coordinating group CH2P(O)Ph2 into the amide part of the molecule leads to an increase in the efficiency of heavy REE(III) extraction and a decrease in the efficiency of light REE(III), and also Th(IV) and U(VI) extraction from nitric acid solutions. The degree of REE(III), U(VI), and Th(IV) extraction into the organic phase by the carbamoylmethylphosphine oxides increases significantly in the presence of the ionic liquid 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide.

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Funding

The work was carried out with the support of the Ministry of Science and Higher Education of the Russian Federation within the framework of the state assignment of Yu.A. Osipyan Institute of Solid State Physics of Russian Academy of Sciences, Institute of Microelectronics Technology and High Purity Materials of Russian Academy of Sciences, Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute,” National Research Centre “Kurchatov Institute,” and A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences.

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Authors and Affiliations

  1. Yu.A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    A. N. Turanov

  2. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    V. K. Karandashev & V. A. Khvostikov

  3. Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”, 107076, Moscow, Russia

    K. V. Tcarkova & N. A. Bondarenko

  4. National Research Centre “Kurchatov Institute”, 123182, Moscow, Russia

    K. V. Tcarkova & N. A. Bondarenko

  5. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    E. V. Sharova & O. I. Artyushin

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  1. A. N. Turanov
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  2. V. K. Karandashev
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Correspondence to N. A. Bondarenko.

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Turanov, A.N., Karandashev, V.K., Khvostikov, V.A. et al. Extraction of REE(III), U(VI), and Th(IV) with Modified Carbamoylmethylphosphine Oxides from Nitric Acid Solutions. Russ J Gen Chem 92, 1049–1055 (2022). https://doi.org/10.1134/S1070363222060160

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