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Effect of Synthesis Conditions on the Regularities of Formation of Arylenephthalide–Styrene Copolymers

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Abstract

Thermally initiated polymerization (120°С) of styrene in the presence of polyarylenephthalides containing the diphenyloxide fragments with different ratios of two adjacent (“head-to-head”) and single (“head-to-tail”) phthalide groups has been performed. Dependence of the polymerization system characteristics and reaction products composition on chemical structure and molecular mass of the starting copolyarylenephthalides, the reaction duration, and the mass ratio of the components in the mixture has been studied. The data of structural-morphological studies of the copolymers of different compositions are presented.

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ACKNOWLEDGMENTS

Authors acknowledge S.V. Veselova (Institute of Biochemistry and Genetics, Ufa Federal Research Center of RAS) for the assistance with laser scanning microscopy imaging.

Funding

This study was performed in the scope of the State Task no. 1021062311389-5-1.4.4 using the equipment of the Center for Collective Usage “Chemistry,” Ufa Federal Research Center of Russian Academy of Sciences.

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Authors and Affiliations

  1. Ufa Institute of Chemistry, Ufa Federa1 Research Center of the Russian Academy of Sciences, 450054, Ufa, Russia

    A. R. Ayupova, T. A. Yangirov, R. Kh. Yumagulova, A. A. Fatykhov & V. A. Kraikin

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  1. A. R. Ayupova
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  2. T. A. Yangirov
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  3. R. Kh. Yumagulova
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Correspondence to R. Kh. Yumagulova.

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Ayupova, A.R., Yangirov, T.A., Yumagulova, R.K. et al. Effect of Synthesis Conditions on the Regularities of Formation of Arylenephthalide–Styrene Copolymers. Russ J Gen Chem 92, 996–1004 (2022). https://doi.org/10.1134/S1070363222060111

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