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Research of the Reaction of Pyromellitic Dianhydride with [3-(Aminomethyl)bicyclo[2.2.1]hept-2-yl]anilines by Calorimetric Method

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Abstract

For the first time, a study of the reaction of pyromellitic dianhydride with [3-(aminomethyl)bicyclo[2.2.1]hept-2-yl]anilines by the calorimetric method was carried out. The enthalpies, rate constants and activation energies of the reaction were determined. It was found that the reactivity in the reactions of the formation of polyamide acids, [3-(aminomethyl)bicyclo[2.2.1]hept-2-yl]anilines are significantly superior to aromatic diamines. It was shown that in the case of 3-[3-(aminomethyl)bicyclo[2.2.1]hept-2-yl]aniline pKa values do not fully take into account steric factors and, therefore, are not a sufficiently sensitive measure of the reactivity of [3-(aminomethyl)bicyclo[2.2.1]hept-2-yl]anilines in the reactions of polyamide acids formation.

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  1. Volgograd State Technical University, 400005, Volgograd, Russia

    I. А. Novakov, B. S. Orlinson, R. V. Brunilin, A. A. Gorbunkova & I. A. Koliev

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  1. I. А. Novakov
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  2. B. S. Orlinson
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  3. R. V. Brunilin
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  4. A. A. Gorbunkova
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  5. I. A. Koliev
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Correspondence to R. V. Brunilin.

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Novakov, I.А., Orlinson, B.S., Brunilin, R.V. et al. Research of the Reaction of Pyromellitic Dianhydride with [3-(Aminomethyl)bicyclo[2.2.1]hept-2-yl]anilines by Calorimetric Method. Russ J Gen Chem 92, 6–9 (2022). https://doi.org/10.1134/S1070363222010029

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