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Vanillinato-Substituted Monospirocyclotriphosphazenes: Synthesis, Spectroscopic and Crystallographic Characterizations, and Thermal Properties

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Abstract

The reactions of one equimolar amount of monospirocyclotriphosphazenes bearing 2,2′-dioxybiphenyl with one, two, three and four equimolar amounts of potassium vanillinate were used to produce the vanillinato-substituted monospirocyclotriphosphazenes. The structures of new phosphazene derivatives were characterized by means of elemental analysis, IR and NMR (1H, 13C, and 31P) spectroscopic techniques. The molecular and crystal structures of mono and tetra vanillinato-substituted monospirocyclotriphosphazenes were examined using X-ray crystallography. The thermal degradation properties of all new compounds were determined using thermal gravimetric analysis (TGA) techniques.

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Funding

This work was financially supported by “Karabük University-BAP” Grant no. KBÜBAP-17-YL-440.

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  1. Department of Chemistry, Faculty of Science, Karabuk University, 78050, Karabuk, Turkey

    Y. Tümer & S. Z. Özdemir

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Tümer, Y., Özdemir, S.Z. Vanillinato-Substituted Monospirocyclotriphosphazenes: Synthesis, Spectroscopic and Crystallographic Characterizations, and Thermal Properties. Russ J Gen Chem 91, 2554–2563 (2021). https://doi.org/10.1134/S1070363221120276

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