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Preparation and Properties of Organo-Silicon-Phosphorus Hybrid Compounds Based on 3-Aminopropyltriethoxysilane, Tetraethoxysilane, and (1-Hydroxyethylidene)diphosphonic Acid

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Abstract

The reaction of 3-aminopropyltriethoxysilane with (1-hydroxyethylidene)diphosphonic acid in 96% ethanol results in the 3-hydroxy(ethoxy)silylpropylaminium salt of (1-hydroxyethylidene)diphosphonic acid. The compound dissolves in water and is regenerated after evaporation and drying in air and in vacuum. The initial low-porous xerogel and the products of its pyrolysis in air and in an inert atmosphere are amorphous phases with impurities of crystalline components. The reaction of tetraethoxysilane with (1-hydroxyethylidene)diphosphonic acid leads to a completely amorphous non-porous condensation product, which loses 57% of its weight after treatment with water.

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Funding

The studies were carried out within the framework of the state assignment (topic no. 45.8 “Chemistry of functional materials,” reg. no. 0094-2016-0012) using the equipment of the Analytical Center of G.A. Razuvaev Institute of Organometallic Chemistry of RAS within the framework of the Federal Target Program “Research and Development in Priority Areas of Development of the Scientific and Technological Complex of Russia for 2014–2020” (unique project identifier RFMEFI62120X0040).

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  1. G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    T. I. Kulikova, N. V. Zolotareva, O. V. Novikova & V. V. Semenov

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  1. T. I. Kulikova
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  2. N. V. Zolotareva
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  3. O. V. Novikova
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  4. V. V. Semenov
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Correspondence to V. V. Semenov.

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To the 100th Anniversary of M.G. Voronkov

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Kulikova, T.I., Zolotareva, N.V., Novikova, O.V. et al. Preparation and Properties of Organo-Silicon-Phosphorus Hybrid Compounds Based on 3-Aminopropyltriethoxysilane, Tetraethoxysilane, and (1-Hydroxyethylidene)diphosphonic Acid. Russ J Gen Chem 91, 2441–2446 (2021). https://doi.org/10.1134/S1070363221120124

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