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Alkylacetylenes in Mercuration-Demercuration Reactions with 1,3-Dicarbonyl Compounds

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Abstract

The reactions of nucleophilic addition of СН-acids to terminal alkynes under electrophilic catalysis with mercury(II) acetate were studied. As a result of mercury-demercuration reactions, the corresponding aromatic and linear derivatives were obtained. A method was proposed for the regeneration of the resulting amorphous mercury by reduction into mercury(II) acetate.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia, 0014, Yerevan, Armenia

    N. G. Hobosyan, K. V. Balyan, A. R. Pogosyan & A. B. Sargsyan

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  1. N. G. Hobosyan
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  2. K. V. Balyan
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  3. A. R. Pogosyan
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  4. A. B. Sargsyan
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Correspondence to N. G. Hobosyan.

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No conflict of interest was declared by the authors.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 11, pp. 1643–1649 https://doi.org/10.31857/S0044460X21110019.

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Hobosyan, N.G., Balyan, K.V., Pogosyan, A.R. et al. Alkylacetylenes in Mercuration-Demercuration Reactions with 1,3-Dicarbonyl Compounds. Russ J Gen Chem 91, 2123–2128 (2021). https://doi.org/10.1134/S1070363221110013

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  • DOI: https://doi.org/10.1134/S1070363221110013

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