Abstract
Acid-base properties of 2,2′-{[(diisopropoxyphosphoryl)methyl]azanediyl}diacetic acid and its complexing ability towards alkaline-earth and transition metals have been studied by means of potentiometric titration. Comparative analysis of the determined stability constants and these of iminodiacetic and nitrilotriacetic acids has been performed. In comparison with iminodiacetic acid, the studied ligand has formed stronger complexes with alkaline earth metal ions and weaker complexes with transition metal ions; its complexes with the investigated cations have been weaker than these of nitrilotriacetic acid.
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REFERENCES
Dyatlova, N.M., Temkina, V.Ya., and Popov, K.I., Kompleksony i kompleksonaty metallov (Complexones and Complexonates of Metals), Miscow: Khimiya, 1988.
Kropacheva, T.N., Shadrin, A.V., Batueva, E.V., and Kornev, V.I., Vestn. Tekhnol. Univ., 2018, vol. 21, no. 6, p. 92.
Skvortsov, S.S., Vasil’ev, A.S., Yakovleva, S.V., Lesnykh, P.A., and Chumakova, E.N., Usp. Sovr. Estestvozn., 2018, vol. 12, no. 2, p. 315.
Semenov, D.I. and Tregubenko, I.P., Kompleksony v biologii i meditsine (Complexones in Biology and Medicine), Sverdlovsk: UNTs AN SSSR, 1984.
Garifzyanov, A.R., Petrov, S.N., Shurygin, I.D. Ivshin, K.A., Kataeva, O.N., and Cherkasov, R.A., Russ. J. Gen. Chem., 2017, vol. 87, no. 2, p. 362. https://doi.org/10.1134/S1070363217020372
Nancollas, G.H. and Tomson, M.B., Pure Appl. Chem., 1982, vol. 54, no. 12. 2675. https://doi.org/10.1351/pac198254122675
Martell, A.E. and Smith, R.M., Critical Stability Constants, New York: Plenum Press, 1974, vol. 1, p. 469.
Cherkasov, R.A., Garifzyanov, A.R., Devyatov, F.V., Kurnosova, N.V., Rahmaeva, A.I., and Davletshin, R.R., Russ. J. Gen. Chem., 2012, vol. 82, no. 9, p. 1492. https://doi.org/10.1134/S107036321209006X
Anderegg, G., Pure Appl. Chem., 1982, vol. 54, no. 12, p. 2693. https://doi.org/10.1351/pac198254122693
Stella, R. and Ganzerli Valentini, M.T., Anal. Chim. Acta, 1983, vol. 152, p. 191. https://doi.org/10.1016/s0003-2670(00)84908-9
Dimmock, P.W., Warwick, P., and Robbins, R.A., Analyst., 1995, vol. 120, no. 8, p. 2159. https://doi.org/10.1039/AN9952002159
Cabaniss, S.E., Environ. Sci. Technol., 2008, vol. 42, no. 14, p. 5210.
Carbonaro, R.F., Atalay, Y.B., and Di Toro, D.M., Geochim. Cosmochim. Acta, 2011, vol. 75, no. 9, p. 2499. https://doi.org/10.1016/j.gca.2011.02.027
Schwarzenbach, G. and Flaschka, H.A., Complexometric Titrations, Methuen, 1969.
Sal’nikov, Yu.I., Glebov, A.N., and Devyatov, F.V., Poliyadernye kompleksy v rastvorakh (Polynuclear Complexes in Solutions), Kazan: KGU, 1989.
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This study was financially supported by the Russian Foundation for Basic Research (project no. 20-33-90235).
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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 10, pp. 1609–1616 https://doi.org/10.31857/S0044460X21100188.
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Mirzayanov, I.I., Garifzyanov, A.R. & Devyatov, F.V. Acid-Base and Complexing Properties of 2,2′-{[(Diisopropoxyphosphoryl)methyl]azanediyl}diacetic Acid. Russ J Gen Chem 91, 2045–2051 (2021). https://doi.org/10.1134/S1070363221100182
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DOI: https://doi.org/10.1134/S1070363221100182