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One-Step Synthesis of 2-[(2-Carboxyphenyl)amino]-6-formylnicotinic Acid via Photolysis of 2-Azidobenzoic Acid in the Presence of Weak Bases

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Abstract

2-Azidobenzoic acid has undergone rearrangement into 2-[(2-carboxyphenyl)amino]-6-formylnicotinic acid under irradiation in aqueous-organic media in the presence of acetates of alkali or alkaline earth metals. The structure of the resulting compound has been elucidated by methods of mass and NMR spectroscopy.

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Authors and Affiliations

  1. National Research Lobachevsky State University of Nizhny Novgorod, 603950, Nizhny Novgorod, Russia

    A. V. Budruev, M. A. Giricheva, D. A. Davydov & A. V. Pokrovskaia

  2. Reper-NN Ltd., 603003, Nizhny Novgorod, Russia

    D. Yu. Dzhons

Authors
  1. A. V. Budruev
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  2. D. Yu. Dzhons
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  3. M. A. Giricheva
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  4. D. A. Davydov
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  5. A. V. Pokrovskaia
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Correspondence to A. V. Budruev.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 10, pp. 1573–1579 https://doi.org/10.31857/S0044460X21100139.

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Budruev, A.V., Dzhons, D.Y., Giricheva, M.A. et al. One-Step Synthesis of 2-[(2-Carboxyphenyl)amino]-6-formylnicotinic Acid via Photolysis of 2-Azidobenzoic Acid in the Presence of Weak Bases. Russ J Gen Chem 91, 2013–2018 (2021). https://doi.org/10.1134/S1070363221100133

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  • DOI: https://doi.org/10.1134/S1070363221100133

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