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Spectral Study of the Effect of Water on the Complex Formation of Photochromic Spiropyrans with Metal Ions in Acetonitrile

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Abstract

A comparative spectral study of the complex formation of molecules of nitro-substituted indoline spiropyrans with metal ions in acetonitrile and water–acetonitrile solutions, and also in acid-containing acetonitrile, was carried out. It was shown that metal complexes are not formed in the presence of water, due to protonation of photochromic spiropyran molecules. Spectral and photochromic properties of the protonated complexes obtained in the presence of water differ from those of protonated complexes arising upon interaction with an acid. A photochromic method for detecting metal ions in aqueous solutions was proposed.

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ACKNOWLEDGMENTS

The authors are grateful to A.R. Tuktarov for providing a sample of 1′-(2-hydroxyethyl)-3′,3′-dimethylspiro[2H-1-benzopyran-2,2′-indoline].

Funding

This work was carried out with the support of the Ministry of science and higher education in the framework of the work on the state order to the Federal research center “Crystallography and photonics” of the Russian academy of sciences.

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Authors and Affiliations

  1. Photochemistry Center, Federal Scientific Recearch Center “Crystallography and Photonics” of the Russian Academy of Sciences, 119421, Moscow, Russia

    О. V. Venidiktova, Т. М. Valova, А. М. Gorelik & V. А. Barachevsky

  2. Interdepartment Center of Analytical Research in Physics, Chemistry and Biology at the Presidium of the Russian Academy of Sciences, 117997, Moscow, Russia

    V. А. Barachevsky

Authors
  1. О. V. Venidiktova
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  2. Т. М. Valova
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  3. А. М. Gorelik
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  4. V. А. Barachevsky
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Correspondence to V. А. Barachevsky.

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No conflict of interest was declared by the authors.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 8, pp. 1253–1260 https://doi.org/10.31857/S0044460X21080138.

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Venidiktova, О.V., Valova, Т.М., Gorelik, А.М. et al. Spectral Study of the Effect of Water on the Complex Formation of Photochromic Spiropyrans with Metal Ions in Acetonitrile. Russ J Gen Chem 91, 1519–1525 (2021). https://doi.org/10.1134/S1070363221080132

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  • DOI: https://doi.org/10.1134/S1070363221080132

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