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Synthesis, Crystal Structures, and Magnetic Properties of Two Manganese(II)/Cobalt(II) Coordination Polymers Constructed by Nitrogenous Carboxylic Acid

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Abstract

Two new coordination polymers, {[Mn2(L)(H2O)2]·H2O}n (1) and {[Co2(L)(H2O)2]·H2O}n (2) (H4L = 2-(2,4,6-tricarboxylphenyl)-6-carbxoylbenzimi-dazole), have been synthesized under hydrothermal conditions and characterized by element analysis, powder XRD and single crystal X-ray diffraction. The results indicate complex 1 as a 2D carboxylate layer structure, which is extended by hydrogen bonds resulting in a three-dimensional supramolecular network. The structure of 2 is isomorphic to that of 1. Magnetic measurements demonstrate weak antiferromagnetic interactions between the neighbouring Mn(II) ions in 1.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, 471934, Luoyang, China

    Y. P. Li, G. L. Li, L. Y. Xin, X. L. Li & G. Z. Liu

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  1. Y. P. Li
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  2. G. L. Li
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  3. L. Y. Xin
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  4. X. L. Li
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Correspondence to G. Z. Liu.

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Li, Y.P., Li, G.L., Xin, L.Y. et al. Synthesis, Crystal Structures, and Magnetic Properties of Two Manganese(II)/Cobalt(II) Coordination Polymers Constructed by Nitrogenous Carboxylic Acid. Russ J Gen Chem 91, 1397–1402 (2021). https://doi.org/10.1134/S1070363221070197

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