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Synthesis and Structure of Antimony Complex Compounds [(4-N,N-Me2C6H4)3MeSb]I and [(4-N,N-Me2C6H4)3MeSb]2[Hg2I6]·2DMSO

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Abstract

It was first found that the alkylation of tris(4-N,N-dimethylaminophenyl)stibine with methyliodide leads to the formation of tris(4-N,N-dimethylaminophenyl)methylstibonium iodide which decomposes in hot water to tris(4-N,N-dimethylaminophenyl)stibine. The reaction of [(4-N,N-Me2C6H4)3MeSb]I with HgI2 in DMSO yields [(4-N,N-(Me)2C6H4)3MeSb]2[Hg2I6]·2DMSO, in which a significant distortion of the tetrahedral cation coordination is caused by the additional interaction of the oxygen atom of the DMSO molecule with the antimony atom.

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ACKNOWLEDGMENTS

The authors of the work express their gratitude to the Center of the Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences for the Study of the Structure of Molecules and the Chemical Service Center for Collective Use of the SB RAS for conducting X-ray diffraction analysis.

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Authors and Affiliations

  1. Blagoveschensk State Pedagogical University, 675000, Blagoveschensk, Russia

    I. V. Egorova, V. V. Zhidkov, I. P. Grinishak & N. А. Rodionova

  2. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    I. Yu. Bagryanskaya

  3. A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    N. V. Pervukhina

Authors
  1. I. V. Egorova
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  2. V. V. Zhidkov
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  3. I. P. Grinishak
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  4. N. А. Rodionova
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  5. I. Yu. Bagryanskaya
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  6. N. V. Pervukhina
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Correspondence to I. V. Egorova.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 7, pp. 1100–1107 https://doi.org/10.31857/S0044460X21070143.

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Egorova, I.V., Zhidkov, V.V., Grinishak, I.P. et al. Synthesis and Structure of Antimony Complex Compounds [(4-N,N-Me2C6H4)3MeSb]I and [(4-N,N-Me2C6H4)3MeSb]2[Hg2I6]·2DMSO. Russ J Gen Chem 91, 1361–1367 (2021). https://doi.org/10.1134/S1070363221070148

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