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Coordination Properties and Fluorescence of a Structurally Novel Zn(II) Pyridine-Terminal Salamo-Type Coordination Polymer

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Abstract

A novel two-dimensional Zn(II) coordination polymer [Zn(II) CP], [{Zn(L)Zn(OAc–)(µ-OAc–)}4]n· 2nCH3CH2OH has been self-assembled from Zn(OAc)2·2H2O. It contains pyridine-terminal salamo-type ligand H2L. Structure of the product has been determined. The Zn(II)CP contains two kinds of Zn(II) ions of different coordination modes. The Zn1 center is characterized by five-coordinated triangular biconical geometry. The Zn2 center is a six-coordinated octahedral center. Using these as junction points and the fully deprotonated ligand (L)2– moieties containing pyridine-terminal as a linker, the 2-D coordination polymer with two kinds of different pores [27.47 × 11.77(23) Å2; 11.97 × 4.51(17) Å2] has been obtained. The Zn(II) CP can fluoresce green and be used in fluorescent materials. Short-range interactions on Zn(II) CP surface have been studied by Hirshfeld surface analysis.

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Funding

This work was supported by the National Natural Science Foundation of China (21761018), which are gratefully acknowledged. Computations were done using National Supercomputing Center in Shenzhen, P. R. China.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, Gansu, China

    L.-L. Li, S.-S. Feng, J.-Q. Zhang, J.-F. Wang & W.-K. Dong

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  1. L.-L. Li
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  2. S.-S. Feng
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  3. J.-Q. Zhang
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  4. J.-F. Wang
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  5. W.-K. Dong
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Correspondence to W.-K. Dong.

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Li, LL., Feng, SS., Zhang, JQ. et al. Coordination Properties and Fluorescence of a Structurally Novel Zn(II) Pyridine-Terminal Salamo-Type Coordination Polymer. Russ J Gen Chem 91, 1128–1134 (2021). https://doi.org/10.1134/S1070363221060220

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