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Highly Selective Schiff-Base Fluorescent Probe for Rare Earth Ion Lu3+

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Abstract

A novel Schiff base fluorescent probe for rare earth ion Lu3+ is reported. Emission intensity of the probe is intrinsically non-fluorescent, which is due to isomerization of the C=N bond in the excited-state proton transfer (ESPT) of phenolic protons of the salicylic amide moiety. In the presence of Lu3+, fluorescence intensifies significantly due to inhibition of the C=N isomerization and ESPT. The Schiff base is characterized by high sensitivity and selectivity towards Lu3+. The fluorescence turn-on mechanism of Lu[L]2 system is proposed.

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Funding

This work was financially supported by the National Natural Science Foundation of China (21501106), the Scientific Research Foundation for the Returned Overseas Chinese Scholars and Qingdao Municipal Science and Technology Commission (16-5-1-86-jch, 19-6-2-73-cg), Chemistry Faculty Talents Foundation of Qingdao University of Science and Technology.

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Authors and Affiliations

  1. College of Environment and Safety Engineering, Qingdao University of Science and Technology, Shandong Province, 266042, Qingdao, China

    Xiaolei Liu, Fei Xu & Lina Wang

  2. College of Materials Science and Engineering, Qingdao University of Science and Technology, 266042, Qingdao, China

    Manhong Liu

  3. Institute of Environmental Planning, Mimistry of Ecology and Environment, 100012, Beijing, China

    Xiaohong Peng

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  1. Xiaolei Liu
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  2. Xiaohong Peng
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  3. Fei Xu
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  4. Lina Wang
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Correspondence to Lina Wang or Manhong Liu.

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Liu, X., Peng, X., Xu, F. et al. Highly Selective Schiff-Base Fluorescent Probe for Rare Earth Ion Lu3+. Russ J Gen Chem 91, 1093–1098 (2021). https://doi.org/10.1134/S1070363221060165

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