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Effect of Composition and Structure of Element Oxide Nanostructures Grafted at Polyethylene Film Surface on Electret Characteristics of the Polymer

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Abstract

Two-component element oxide nanostructures differing in composition and mutual arrangement of phosphorus and titanium oxide groups have been synthesized at the surface of high-pressure polyethylene films via the molecular layering method by treating the polymer with TiCl4, POCl3, and H2O vapors in predefined order. Using atomic force microscopy and thermally stimulated relaxation of the surface potential methods, it has been shown that the sequence of formation of element oxide structures in the two-component systems significantly effects the stability of the polyethylene electret properties.

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REFERENCES

  1. Sirota, A.G., Modifications of Structure and Properties of Polyolefins, Jerusalem: Israel Program for Scientific Translations, 1985.

  2. Polyakov, A.V., Duntov, F.I., Sofiev, A.E., and Tumarkin, N.Ya., Polietilen vysokogo davleniya. Nauchno-tekhnicheskie osnovy promyshlennogo sinteza (High Pressure Polyethylene. Scientific and Technical Foundations of Industrial Synthesis), Leningrad: Khimiya, 1988.

  3. Povstugar, V.I., Kodolov, V.I., and Mikhailova, S.S., Stroenie i svoistva poverkhnosti polimernykh materialov (The Structure and Properties of the Surface of Polymeric Materials), Moscow: Khimiya, 1988.

  4. Bergbreiter, D.E., Prog. Polym. Sci., 1994, vol. 19, no. 3, p. 529. https://doi.org/10.1016/0079-6700(94)90004-3

    Article  CAS  Google Scholar 

  5. Desai, S.M. and Singh, R.P., Adv. Polym. Sci., 2004, vol. 169, p. 231. https://doi.org/10.1007/b13524

    Article  CAS  Google Scholar 

  6. Sirota, A.G. and Bugorkova, V.S., Int. Polym. Sci. Technol., 2011, vol. 38, no. 7, p. 1. https://doi.org/10.1177/0307174X1103800701

    Article  Google Scholar 

  7. Asadinezhad, A., Lehockу, M., Sаha, P., and Mozetiс, M., Materials, 2012, vol. 5, no. 12, p. 2937. https://doi.org/10.3390/ma5122937

    Article  CAS  PubMed Central  Google Scholar 

  8. Aleskovskii, V.B., Khimiya nadmolekulyarnykh soedinenii (Chemistry of Supramolecular Compounds), St. Petersburg: SPbGU, 1996.

  9. Malygin, А.А., Маlkov, А.А., and Sosnov, Е.А., Russ. Chem. Bull., 2017, vol. 66, no. 11, p. 1939. https://doi.org/10.1007/s11172-017-1971-9

    Article  CAS  Google Scholar 

  10. Sessler, G.M., Electrets, Heidelberg: Springer, 1980, p. 13. https://doi.org/10.1007/3540173358_10

  11. Electrets, Gerhard-Multhaupt, R., Ed., Morgan Hill: Laplacian Press, 1999. Vol.2. 338 p.

  12. Rychkov D.A, Kuznetsov, A.E., and Rychkov, A.A., Stabilizatsiya zaryada polimernykh elektretov (Stabilization of the Charge of Polymer Electrets), St. Petersburg: RGPU im. Herzen, 2013.

  13. Lushcheikin, G.A., Russ. Chem. Rev., 1983, vol. 52, no. 8, p. 804. https://doi.org/10.1070/RC1983v052n08ABEH002884

    Article  Google Scholar 

  14. Unge, M., Törnkvist, C., and Christen, T., Proc., 2013 IEEE Int. Conf. Solid Dielectrics (ICSD 2013), Bologna, Italy, 2013, p. 935. https://doi.org/10.1109/ICSD.2013.6619874

  15. Rychkov, A.A., Trifonov, S.A., Kuznetsov, A.E., Sosnov, E.A., Rychkov, D.A., and Malygin, A.A., Russ. J. Appl. Chem., 2007, vol. 80, no. 3, p. 461. https://doi.org/10.1134/S1070427207030214

    Article  CAS  Google Scholar 

  16. Rychkov, A.A., Rychkov, D.A., Dergachev, V.F., and Kuznetsov, A.E., RF Patent 2477540, 2013, Byull. Izobret., 2013, no. 7.

  17. Trifonov, S.A., Sosnov, E.A., and Malygin, A.A., Russ. J. Appl. Chem., 2004, vol. 77, no. 11, p. 1854. https://doi.org/10.1007/s11167-005-0175-5

    Article  CAS  Google Scholar 

  18. Lobanov, V.V. and Chuiko, A.A., Physical Chemistry of Surfaces, 2001, nos. 4–6, p. 6.

    Google Scholar 

  19. Kao, K.C. and Hwang, W., Electrical Transport in Solids, with Particular Reference to Organic Semiconductors, Oxford: Pergamon Press, 1981.

  20. Meunier, M., Quirke, N., and Aslanides, A., J. Chem. Phys., 2001, vol. 115, no. 6, p. 2876. https://doi.org/10.1063/1.1385160

    Article  CAS  Google Scholar 

  21. Nichugovskii, G.F., Opredelenie vlazhnosti khimicheskikh veshchestv (Determination of Moisture in Chemicals), Leningrad: Khimiya, 1977.

  22. Novikov, G.K., Vestn. IrGTU, 2003, nos. 3–4 (15–16), p. 93.

    Google Scholar 

  23. Ryshhenko, I.M., Rusinov, A.I., and Blinkov, N.A., Vost.-Evrop. Zh. Pered. Tekhnol., 2015, vol. 5, no. 6 (77), p. 29. https://doi.org/10.15587/1729-4061.2015.51359

    Article  Google Scholar 

  24. Chvertkina, L.V., Khoklov, P.S., and Mironov, V.F., Russ. Chem. Rev., 1992, vol. 61, no. 10, p. 1009. https://doi.org/10.1070/RC1992v061n10ABEH001013

    Article  Google Scholar 

  25. Novikov, G.I., Marinova, L.A., and Yaglov, V.N., Russ. J. Phys. Chem. USSR, 1971, vol. 45, no. 2, p. 268.

    Google Scholar 

  26. Volkov, A.I., Komshilova, O.N., Novikov, G.I., and Yaglov, V.N., Khim. Khim. Tekhnol., Minsk: Vysshaya Shkola, 1982, no. 17, p. 34.

  27. Volkov, A.I. and Yaglov, V.N., Khim. Khim. Tekhnol., Minsk: Vysshaya Shkola, 1977, no. 12, p. 17.

  28. D’yakova, A.K., Trifonov, S.A., Sosnov, E.A., and Malygin, A.A., Russ. J. Appl. Chem., 2009, vol. 82, no. 4, p. 622. https://doi.org/10.1134/S107042720904017X

    Article  CAS  Google Scholar 

  29. Simmons, J.G. and Tam, М.С., Phys. Rev. (B), 1973, vol. 7, no. 8, p. 3706. https://doi.org/10.1103/PhysRevB.7.3706

    Article  CAS  Google Scholar 

  30. Rychkov, A.A., Kuznetsov, A.E., and Ivanov, V.A., Fund. Probl. Radioelektron. Priborostroen., 2015, vol. 15, no. 2, p. 96.

    Google Scholar 

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Funding

This study was performed using the equipment of the First All-Russia Engineering Center for Molecular Layering Technology, St. Petersburg State Institute of Technology (agreement no. 075-15-2021-028, MMinistry of Science and Higher Education of Russia).

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology (Technical University), 190013, St. Petersburg, Russia

    A. S. Tsipanova, E. A. Sosnov & A. A. Malygin

  2. Herzen State Pedagogical University of Russia, 191186, St. Petersburg, Russia

    A. E. Kuznetsov & A. A. Rychkov

Authors
  1. A. S. Tsipanova
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  2. E. A. Sosnov
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  3. A. E. Kuznetsov
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  4. A. A. Rychkov
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  5. A. A. Malygin
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Corresponding author

Correspondence to E. A. Sosnov.

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A.A. Malygin is the member of Editorial Board of the Russian Journal of General Chemistry. No conflict of interest was declared by other authors.

Additional information

Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 6, pp. 966–976 https://doi.org/10.31857/S0044460X21060147.

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Tsipanova, A.S., Sosnov, E.A., Kuznetsov, A.E. et al. Effect of Composition and Structure of Element Oxide Nanostructures Grafted at Polyethylene Film Surface on Electret Characteristics of the Polymer. Russ J Gen Chem 91, 1075–1083 (2021). https://doi.org/10.1134/S1070363221060141

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  • DOI: https://doi.org/10.1134/S1070363221060141

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