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Tris(3-fluorophenyl)antimony Dihalides: Synthesis and Structure

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Abstract

Tris(3-fluorophenyl)antimony dichloride, dibromide, and diiodide were obtained by the reaction of tris(3-fluorophenyl)antimony with chlorine, bromine, and iodine in benzene. Dichloride and dibromide were also obtained in the reaction of tris(3-fluorophenyl)antimony with copper dihalides in acetone. Tris(3-fluorophenyl)antimony difluoride was obtained in the exchange reaction between tris(3-fluorophenyl)antimony dichloride and sodium fluoride. According to single crystal X-ray diffraction data, centrosymmetric dichloride and dibromide molecules and four types of crystallographically independent diiodide molecules have a trigonal-bipyramidal configuration with electronegative ligands in axial positions.

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  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin & O. K. Sharutina

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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Correspondence to V. V. Sharutin.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 5, pp. 752–757 https://doi.org/10.31857/S0044460X21050127.

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Sharutin, V.V., Sharutina, O.K. Tris(3-fluorophenyl)antimony Dihalides: Synthesis and Structure. Russ J Gen Chem 91, 835–839 (2021). https://doi.org/10.1134/S1070363221050121

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