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Effect of the Loading of Metal Salts on the Formation of Fe–Co Solid Solution Nanoparticles in the IR-Pyrolyzed Chitosan Matrix

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Abstract

In this study, metal-carbon nanocomposites have been synthesized via the method of simultaneous formation of bimetallic Fe–Co nanoparticles and carbon support based on pyrolyzed chitosan under the IR irradiation. The XRD structural characteristics as well as morphology and dispersity of Fe–Co nanoparticles depending on the loading of metals in the nanocomposites have been studied. It has been shown that the increase in the metal salts loading in the precursor leads to the formation of metal nanoparticles of larger size and more homogeneous composition of the Fe–Co solid solution. Detailed analysis of the XRD peaks of the obtained Fe–Co phase has allowed to distinguish them into several phases of a solid solution based on body-centered cubic and face-centered cubic lattices.

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Funding

This work was carried out within the State Program of TIPS RAS.

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Authors and Affiliations

  1. National University of Science and Technology “MISiS”, 119049, Moscow, Russia

    D. V. Bindiug & E. L. Dzidziguri

  2. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Vasilev, M. N. Efimov & G. P. Karpacheva

Authors
  1. D. V. Bindiug
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  2. A. A. Vasilev
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  3. E. L. Dzidziguri
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  4. M. N. Efimov
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  5. G. P. Karpacheva
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Correspondence to D. V. Bindiug.

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Bindiug, D.V., Vasilev, A.A., Dzidziguri, E.L. et al. Effect of the Loading of Metal Salts on the Formation of Fe–Co Solid Solution Nanoparticles in the IR-Pyrolyzed Chitosan Matrix. Russ J Gen Chem 91, 108–114 (2021). https://doi.org/10.1134/S1070363221010126

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  • DOI: https://doi.org/10.1134/S1070363221010126

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