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Polyfunctional Ionochromic 1,3-Dihydroxy-6-oxo-6H-benzo[c]chromene-2,4-dicarbaldehyde Aroylhydrazones

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Abstract

Bisaroylhydrazones of a novel 1,3-dihydroxy-6-oxo-6H-benzo[c]chromene-2,4-dicarbaldehyde have been synthesized. The obtained compounds represent multifunctional chemosensors capable of detecting fluoride, cyanide, and acetate anions as well as transition metal cations. The formation of complexes with anions has led to a change in the color of the solution in DMSO from light yellow to orange-red. The addition of bivalent nickel, cobalt, or zinc chlorides has changed the solution color to orange. At the same time, the initial fluorescence has been significantly quenched.

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Funding

The research was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the scope of the governmental task in the field of science (no. 0852-2020-0019) and in the scope of the governmental task to the Southern Scientific Center of RAS (no. 01201354239, A.D. Dubonosov).

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia

    O. G. Nikolaeva, O. Yu. Karlutova, V. A. Bren & V. I. Minkin

  2. Federal Research Center “The Southern Scientific Center of the Russian Academy of Sciences”, 344006, Rostov-on-Don, Russia

    A. D. Dubonosov

Authors
  1. O. G. Nikolaeva
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  2. O. Yu. Karlutova
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  3. A. D. Dubonosov
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  4. V. A. Bren
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  5. V. I. Minkin
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Correspondence to A. D. Dubonosov.

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Nikolaeva, O.G., Karlutova, O.Y., Dubonosov, A.D. et al. Polyfunctional Ionochromic 1,3-Dihydroxy-6-oxo-6H-benzo[c]chromene-2,4-dicarbaldehyde Aroylhydrazones. Russ J Gen Chem 90, 2219–2224 (2020). https://doi.org/10.1134/S1070363220120014

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