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Luminescent Sensor for Cr2O72–: A Novel Coordination Polymer Based on Flexible Homophthalic Acid

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Abstract

A novel luminescence coordination polymer [Zn(hmph)(bibp)]n (1) has been synthesized by mild solvothermal method. It crystallizes in the orthorhombic space group Pbca with a = 17.304(3) Å, b = 11.2628(18) Å, c = 33.951(5) Å; α = β = γ = 90°, V = 6616.6(18) Å3, C33H32ZnN6O4, Mr = 642.02, Z = 8, Dc = 1.289 g/cm3, μ = 0.787 mm–1, F(000) = 2672, R1 = 0.0563 and wR2 = 0.1071 with I > 2σ(I), and represents a metal-organic monolayer structure. Thermal stability and luminescence of the product have been studied. Compound 1 can be a promising luminescence-based chemical sensor for Cr2O72– ion based on the quenching mechanism.

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Authors and Affiliations

  1. School of Food and Drug, Luoyang Normal University, 471934, Henan, Luoyang, China

    F. Y. Ju, W. B. Guo & X. X. Wang

  2. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, 471934, Henan, Luoyang, China

    G. Z. Liu

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  2. W. B. Guo
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  4. G. Z. Liu
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Correspondence to G. Z. Liu.

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Ju, F.Y., Guo, W.B., Wang, X.X. et al. Luminescent Sensor for Cr2O72–: A Novel Coordination Polymer Based on Flexible Homophthalic Acid. Russ J Gen Chem 90, 2176–2180 (2020). https://doi.org/10.1134/S1070363220110250

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