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Structure and Energy Profile of the Skeletal Nickel Surface According to the Small-Angle X-Ray Diffraction and Adsorption Calorimetry Data

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

A systematic study of the surface of Raney nickel-based pyrophoric catalysts by small-angle X-ray diffraction analysis was carried out for the first time. The parameters of the crystallites constituting the active catalyst surface were determined. A correlation between the surface structure and the activity of skeletal nickel for the liquid-phase hydrogenation reactions was demonstrated. The effect of treatment of Ni–Al alloy with sodium hydroxide and hydrogen peroxide on the catalyst particle size and on the course of the hydrogenation reaction was revealed and substantiated. The X-ray diffraction data on the catalyst surface structure and the adsorption calorimetry data were correlated with the skeletal nickel activity parameters.

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Funding

The measurement of a catalyst activity and kinetic studies were supported by the Ministry of Science and Higher Education of the Russian Federation (project no. FZZW-2020-0010). Thermochemical studies on a calorimeter to determine the heats of adsorption in hydrogen were implemented with financial support from the Presidential grant for young PhD scientists (project MK-771.2020.3).

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, 153000, Ivanovo, Russia

    V. V. Kuznetsov, T. Yu. Osadchaya, A. V. Afineevskii, D. A. Prozorov & M. V. Lukin

  2. Ivkhimprom Open Joint-Stock Company, 153021, Ivanovo, Russia

    D. N. Smirnova

Authors
  1. V. V. Kuznetsov
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  2. T. Yu. Osadchaya
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  3. A. V. Afineevskii
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  4. D. A. Prozorov
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  5. M. V. Lukin
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  6. D. N. Smirnova
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Corresponding author

Correspondence to D. A. Prozorov.

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Kuznetsov, V.V., Osadchaya, T.Y., Afineevskii, A.V. et al. Structure and Energy Profile of the Skeletal Nickel Surface According to the Small-Angle X-Ray Diffraction and Adsorption Calorimetry Data. Russ J Gen Chem 90, 1787–1794 (2020). https://doi.org/10.1134/S1070363220090327

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