Skip to main content
SpringerLink
Log in

Structure of the Nearest Environment of Na+, K+, Rb+, and Cs+ Ions in Oxygen-Containing Solvents

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The review generalizes and analyzes published data on different methods of studying structural characteristics of the solvation environment of alkali metal ions (except for Li+) in various electron-donor oxygen-containing solvents. Coordination numbers of alkali metal ions, interspecies distances, and types of ion association are discussed. The solvation structures of alkali metal cations in water and some nonaqueous systems are compared. The number of solvent molecules and the distance between the cation and oxygen atom of solvent molecule in the first coordination sphere are independent of physicochemical properties of the solvent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Smirnov, P.R., Russ. J. Gen. Chem., 2019, vol. 89, no. 12, p. 2443. https://doi.org/10.1134/S1070363219120193

    Article  CAS  Google Scholar 

  2. Smirnov, P.R. and Trostin, V.N., Russ. J. Gen. Chem., 2007, vol. 77, no. 5, p. 844. https://doi.org/10.1134/S1070363207050052

    Article  CAS  Google Scholar 

  3. Smirnov, P.R. and Trostin, V.N., Russ. J. Gen. Chem., 2007, vol. 77, no. 12, p. 2101. https://doi.org/10.1134/S1070363207120043

    Article  CAS  Google Scholar 

  4. Zhou, Y., Fang, C., Fang, Y., Zhu, F., Tao, S., and Xu, S.,Russ. J. Phys. Chem. A, 2012, vol. 86, no. 8, p. 1236. https://doi.org/10.1134/S0036024412060349

    Article  CAS  Google Scholar 

  5. Mähler, J. and Persson, I., Inorg. Chem., 2012, vol. 51, no. 1, p. 425. https://doi.org/10.1021/ic2018693

    Article  CAS  PubMed  Google Scholar 

  6. Zhou, Y., Higa, S., Fang, C., Fang, Y., Zhang, W., and Yamaguchi, T., Phys. Chem. Chem. Phys., 2017, vol. 19, p. 27878. https://doi.org/10.1039/C7CP05107G

    Article  CAS  PubMed  Google Scholar 

  7. Galib, M., Baer, M.D., Skinner, L.B., Mundy, C.J., Huthwelker, T., Schenter, G.K., Benmore, C.J., Govind, N., Fulton, J.L., J. Chem. Phys., 2017, vol. 146, article ID 084504. https://doi.org/10.1063/1.4975608

  8. Zhou, Y., Yamaguchi, T., Yoshida, K., Fang, C., Fang, Y., and Zhu, F., J. Mol. Liq., 2019, vol. 274, p. 173. https://doi.org/10.1016/j.molliq.2018.10.124

    Article  CAS  Google Scholar 

  9. Beladjine, S., Amrani, M., Zanoun, A., Belaidi, A., and Vergoten, G., Comput. Theor. Chem., 2011, vol. 977, nos. 1–3, p. 97. https://doi.org/10.1016/j.comptc.2011.09.010

    Article  CAS  Google Scholar 

  10. Hartkamp, R. and Coasne, B., J. Chem. Phys., 2014, vol. 141, no. 12, article ID 124508. https://doi.org/10.1063/1.4896380

  11. Neela, Y.I., Mahadevi, A.S., and Sastry, G.N., Struct. Chem., 2013, vol. 24, no. 1, p. 67. https://doi.org/10.1007/s11224-012-0032-0

    Article  CAS  Google Scholar 

  12. Zhou, Y., Fang, C., Fang, Y., Zhu, F., Ge, H., and Liu, H.,Russ. J. Phys. Chem. A, 2017, vol. 91, no. 13, p. 2539. https://doi.org/10.1134/S0036024417130313

    Article  CAS  Google Scholar 

  13. Teychené, J., Roux-de Balmann, H., Maron, L., and Galier, S.,ACS Cent. Sci., 2018, vol. 4, no. 11, p. 1531. https://doi.org/10.1021/acscentsci.8b00610

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  14. Teychene, J., Roux-de Balmann, H., Maron, L., and Galier, S.,J. Mol. Liq., 2019, vol. 294, article ID 111394. https://doi.org/10.1016/j.molliq.2019.111394

  15. Zeng, Y., Hu, J., Yuan, Y., Zhang, X., and Ju, S., Chem. Phys. Lett., 2012, vol. 538, p. 60. https://doi.org/10.1016/j.cplett.2012.04.035

    Article  CAS  Google Scholar 

  16. Rowley, C.N. and Roux, B., J. Chem. Theory Comput., 2012, vol. 8, no. 10, p. 3526. https://doi.org/10.1021/ct300091w

    Article  CAS  PubMed  Google Scholar 

  17. Lev, B., Roux, B., and Noskov, S.Y., J. Chem. Theory Comput., 2013, vol. 9, no. 9, p. 4165. https://doi.org/10.1021/ct400296w

    Article  CAS  PubMed  Google Scholar 

  18. Sripa, P., Tongraar, A., and Kerdcharoen, T., J. Phys. Chem. A, 2013, vol. 117, no. 8, p. 1826. https://doi.org/10.1021/jp312230g

    Article  CAS  PubMed  Google Scholar 

  19. Bankura, A., Carnevale, V., and Klein, M.L., J. Chem. Phys., 2013, vol. 138, no. 1, article ID 014501. https://doi.org/10.1063/1.4772761

  20. Bankura, A., Carnevale, V., and Klein, M.L., Mol. Phys., 2014, vol. 112, nos. 9–10, p. 1448. https://doi.org/10.1080/00268976.2014.905721

    Article  CAS  Google Scholar 

  21. Gaiduk, A.P., Zhang, C., Gygi, F., and Galli, G., Chem. Phys. Lett., 2014, vol. 604, p. 89. https://doi.org/10.1016/j.cplett.2014.04.037

    Article  CAS  Google Scholar 

  22. Faginas-Lago, N., Lombardi, A., Albertí, M., and Grossi, G.,J. Mol. Liq., 2015, vol. 204, p. 192. https://doi.org/10.1016/j.molliq.2015.01.029

    Article  CAS  Google Scholar 

  23. Gee, M.B., Cox, N.R., Jiao, Y., Bentenitis, N., Weerasinghe, S., and Smith, P.E., J. Chem. Theory Comput., 2011, vol. 7, no. 5, p. 1369. https://doi.org/10.1021/ct100517z

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  24. Chen, H. and Ruckenstein, E., J. Phys. Chem. B, 2015, vol. 119, no. 39, p. 12671. https://doi.org/10.1021/acs.jpcb.5b06837

    Article  CAS  PubMed  Google Scholar 

  25. Liu, C., Min, F., Liu, L., and Chen, J., Chem. Phys. Lett., 2019, vol. 727, p. 31. https://doi.org/10.1016/j.cplett.2019.04.045

    Article  CAS  Google Scholar 

  26. Zhou, L., Xu, J., Xu, L., and Wu, X., J. Chem. Phys., 2019, vol. 150, no. 12, article ID 124505. https://doi.org/10.1063/1.5086939

  27. Smirnov, P.R., Russ. J. Gen. Chem., 2013, vol. 83, no. 11, p. 1967. https://doi.org/10.1134/S1070363213110017

    Article  CAS  Google Scholar 

  28. Naidoo, K.J., Lopis, A.S., Westra, A.N., Robinson, D.J., and Koch, K.R., J. Am. Chem. Soc., 2003, vol. 125, no. 44, p. 13330. https://doi.org/10.1021/ja035326x

    Article  CAS  PubMed  Google Scholar 

  29. Dixit, M.K. and Tembe, B.L., J. Mol. Liq., 2013, vol. 178, p. 78. https://doi.org/10.1016/j.molliq.2012.09.026

    Article  CAS  Google Scholar 

  30. Kloss, A.A. and Fawcett, W.R., J. Chem. Soc., Faraday Trans., 1998, vol. 94, no. 24, p. 1587. https://doi.org/10.1039/A800427G

    Article  CAS  Google Scholar 

  31. He, M., Lau, K.C., Ren, X., Xiao, N., McCulloch, W.D., Curtiss, L.A., and Wu, Y., Angew. Chem., Int. Ed., 2016, vol. 55, p. 15310. https://doi.org/10.1002/anie.201608607

    Article  CAS  Google Scholar 

  32. Rao, B.G. and Singh, U.C., J. Am. Chem. Soc., 1990, vol. 112, no. 10, p. 3803. https://doi.org/10.1021/ja00166a014

    Article  CAS  Google Scholar 

  33. Kalugin, O.N., Volobuev, M.N., Ishchenko, A.V., and Adya, A.K.,J. Mol. Liq., 2000, vol. 85, no. 3, p. 299. https://doi.org/10.1016/S0167-7322(00)89014-5

    Article  CAS  Google Scholar 

  34. Adya, A., Kalugin, O., Volobuev, M., and Kolesnik, Y., Mol. Phys., 2001, vol. 99, no. 10, p. 835. https://doi.org/10.1080/00268970010024867

    Article  CAS  Google Scholar 

  35. Madhusoodanan, M. and Tembe, B.L., J. Phys. Chem., 1994, vol. 98, no. 28, p. 7090. https://doi.org/10.1021/j100079a032

    Article  CAS  Google Scholar 

  36. Madhusoodanan, M. and Tembe, B.L., J. Phys. Chem., 1995, vol. 99, no. 1, p. 44. https://doi.org/10.1021/j100001a009

    Article  CAS  Google Scholar 

  37. Das, A.K. and Tembe, B.L., J. Chem. Phys., 1998, vol. 108, no. 7, p. 2930. https://doi.org/10.1063/1.475680

    Article  CAS  Google Scholar 

  38. Kerisit, S., Vijayakumar, M., Han, K.S., and Mueller, K.T.,J. Chem. Phys., 2015, vol. 142, no. 22, article ID 224502. https://doi.org/10.1063/1.4921982

  39. Patil, U.N., Keshri, S., and Tembe, B.L., J. Mol. Liq., 2015, vol. 207, p. 279. https://doi.org/10.1016/j.molliq.2015.03.048

    Article  CAS  Google Scholar 

  40. Pham, T.A., Kweon, K.E., Samanta, A., Lordi, V., and Pask, J.E.,J. Phys. Chem. C, 2017, vol. 121, no. 40, p. 21913. https://doi.org/10.1021/acs.jpcc.7b06457

    Article  CAS  Google Scholar 

  41. Brooksby, P.A. and Fawcett, W.R., Spectrochim. Acta, Part A, 2006, vol. 64, no. 2, p. 372. https://doi.org/10.1016/j.saa.2005.07.033

    Article  CAS  Google Scholar 

  42. Flores, E., Avall, G., Jeschke, S., and Johansson, P., Electrochim. Acta, 2017, vol. 233, p. 134. https://doi.org/10.1016/j.electacta.2017.03.031

    Article  CAS  Google Scholar 

  43. Cresce, A.V., Russell, S.M., Borodin, O., Allen, J.A., Schroeder, M.A., Dai, M., Peng, J., Gobet, M.P., Greenbaum, S.G., Rogers, R.E., and Xu, K.,Phys. Chem. Chem. Phys., 2017, vol. 19, p. 574. https://doi.org/10.1039/C6CP07215A

    Article  CAS  Google Scholar 

  44. Yu, H., Mazzanti, C.L., Whitfield, T.W., Koeppe, R.E., Andersen, O.S., and Roux, B., J. Am. Chem. Soc., 2010, vol. 132, no. 31, p. 10847. https://doi.org/10.1021/ja103270w

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  45. Pattanayak, S.K. and Chowdhuri, S., J. Theor. Comput. Chem., 2012, vol. 11, no. 2, p. 361. https://doi.org/10.1142/S0219633612500241

    Article  CAS  Google Scholar 

  46. Pattanayak, S.K. and Chowdhuri, S., J. Mol. Liq., 2012, vol. 172, p. 102. https://doi.org/10.1016/j.molliq.2012.05.012

    Article  CAS  Google Scholar 

  47. Wanprakhon, S., Tongraar, A., and Kerdcharoen, T., Chem. Phys. Lett., 2011, vol. 517, nos. 4–6, p. 171. https://doi.org/10.1016/j.cplett.2011.10.048

    Article  CAS  Google Scholar 

  48. Fang, C.H., Zhu, F.Y., Fang, Y., Zhou, Y.Q., Tao, S., and Xu, S.,Phys. Chem. Liq., 2013, vol. 51, no. 2, p. 218. https://doi.org/10.1080/00319104.2012.722061

    Article  CAS  Google Scholar 

  49. Zhu, F.Y., Fang, C.H., Fang, Y., Zhou, Y.Q., Ge, H.W., and Liu, H.Y., J. Mol. Struct., 2014, vol. 1070, p. 80. https://doi.org/10.1016/j.molstruc.2014.04.002

    Article  CAS  Google Scholar 

  50. Gallo, P., Corradini, D., and Rovere, M., J. Mol. Liq., 2014, vol. 189, p. 52. https://doi.org/10.1016/j.molliq.2013.05.023

    Article  CAS  Google Scholar 

  51. Sripa, P., Tongraar, A., and Kerdcharoen, T., Chem. Phys., 2016, vol. 479, p. 72. https://doi.org/10.1016/j.chemphys.2016.09.028

    Article  CAS  Google Scholar 

  52. Li, F., Li, S., Zhuang, X., and Yuan, J., Chem. Eng. Trans. 2017, vol. 61, p. 769. https://doi.org/10.3303/CET1761126

  53. Zhu, F.Y., Fang, C.H., Fang, Y., Zhou, Y.Q., Ge, H.W., and Liu, H.Y., J. Mol. Struct., 2015, vol. 1083, p. 471. https://doi.org/10.1016/j.molstruc.2014.10.041

    Article  CAS  Google Scholar 

  54. Zhu, F., Zhou, H., Zhou, Y., Miao, J., Fang, C., Fang, Y., Sun, P., Ge, H., and Liu, H., Eur. Phys. J. D, 2016, vol. 70, p. 246. https://doi.org/10.1140/epjd/e2016-60529-7

    Article  CAS  Google Scholar 

  55. Li, F., Yuan, J., Li, D., Li, S., and Han, Z., J. Mol. Struct., 2015, vol. 1081, p. 38. https://doi.org/10.1016/j.molstruc.2014.09.062

    Article  CAS  Google Scholar 

  56. Eiberweiser, A., Nazet, A., Hefter, G., and Buchner, R., J. Phys. Chem. B, 2015, vol. 119, no. 16, p. 5270. https://doi.org/10.1021/acs.jpcb.5b01417

    Article  CAS  PubMed  Google Scholar 

  57. Bertagnolli, H., Schultz, H.E., and Chieux, P., Ber. Bunsenges. Phys. Chem., 1989, vol. 93, no. 1, p. 88. https://doi.org/10.1002/bbpc.19890930117

    Article  CAS  Google Scholar 

  58. Siddique, A.A., Dixit, M.K., and Tembe, B.L., J. Mol. Liq., 2013, vol. 188, p. 5. https://doi.org/10.1016/j.molliq.2013.09.004

    Article  CAS  Google Scholar 

  59. Pham, V.T. and Fulton, J.L., J. Chem. Phys., 2013, vol. 138, no. 4, article ID 044201. https://doi.org/10.1063/1.4775588

  60. Pham, V.-T. and Fulton, J.L., J. Solut. Chem., 2016, vol. 45, no. 7, p. 1061. https://doi.org/10.1007/s10953-016-0487-5

    Article  CAS  Google Scholar 

  61. Miao, J.T., Fang, C.H., Fang, Y., Zhu, F.Y., Liu, H.Y., Zhou, Y.Q., Ge, H.W., Sun, P.C., and Zhao, X.C., J. Mol. Struct., 2016, vol. 1109, p. 67. https://doi.org/10.1016/j.molstruc.2015.12.081

    Article  CAS  Google Scholar 

  62. Zhang, W.Q., Fang, C.H., Li, W., Zhou, Y.Q., Zhu, F.Y., and Liu, H.Y., J. Mol. Liq., 2019, vol. 1194, p. 262. https://doi.org/10.1016/j.molstruc.2019.01.019

    Article  CAS  Google Scholar 

  63. Boda, A. and Ali, S.M., J. Mol. Liq., 2013, vol. 179, p. 34. https://doi.org/10.1016/j.molliq.2012.12.007

    Article  CAS  Google Scholar 

  64. Caralampio, D.Z., Martínez, J.M., Pappalardo, R.R., and Marcos, E.S., Phys. Chem. Chem. Phys., 2017, vol. 19, no. 42, p. 28993. https://doi.org/10.1039/C7CP05346K

    Article  CAS  PubMed  Google Scholar 

  65. Hydayat, Y., Pranowo, H.D., and Trisunaryanti, W., J. Mol. Liq., 2020, vol. 298, article ID 112027. https://doi.org/10.1016/j.molliq.2019.112027

  66. Chowdhuri, S. and Chandra, A., J. Chem. Phys., 2006, vol. 124, no. 8, article ID 084507. https://doi.org/10.1063/1.2172598

  67. D’Angelo, P. and Persson, I., Inorg. Chem., 2004, vol. 43, no. 11, p. 3543. https://doi.org/10.1021/ic030310t

    Article  CAS  PubMed  Google Scholar 

  68. Mile, V., Gereben, O., Kohara, S., and Pusztai, L., J. Phys. Chem. B, 2012, vol. 116, no. 32, p. 9758. https://doi.org/10.1021/jp301595m

    Article  CAS  PubMed  Google Scholar 

  69. Zhang, W.Q., Fang, C.H., Fang, Y., Zhu, F.Y., Zhou, Y.Q., Liu, H.Y., and Li, W., J. Mol. Struct., 2018, vol. 1160, p. 26. https://doi.org/10.1016/j.molstruc.2017.12.099

    Article  CAS  Google Scholar 

  70. Pham, V.T. and Fulton, J.L., J. Electron Spectrosc. Relat. Phenom., 2018, vol. 229, p. 20. https://doi.org/10.1016/j.elspec.2018.09.004

    Article  CAS  Google Scholar 

  71. Roy, S. and Bryantsev, V.S., J. Phys. Chem. B, 2018, vol. 122, no. 50, p. 12067. https://doi.org/10.1021/acs.jpcb.8b08414

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045, Ivanovo, Russia

    P. R. Smirnov

Authors
  1. P. R. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. R. Smirnov.

Ethics declarations

The author declares no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Smirnov, P.R. Structure of the Nearest Environment of Na+, K+, Rb+, and Cs+ Ions in Oxygen-Containing Solvents. Russ J Gen Chem 90, 1693–1702 (2020). https://doi.org/10.1134/S1070363220090169

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363220090169

Keywords:

Search

Navigation