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Structure of the Product of 1,3,5,7-Tetra-tert-butyloctahydro-1H,4аH-imidazo[4′,5′:5,6]dioxino[2,3-d]imidazole Cocrystallization with 1,3-Di-tert-butylimidazol-2-one and 1,3-Di-tert-butylimidazolin-2-ylidene

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Abstract

Structure of the product of imidazolidine (1,3,5,7-tetra-tert-butyloctahydro-1H,4аH-imidazo[4ʹ,5ʹ:5,6]dioxino[2,3-d]imidazole) ether cocrytallization with 1,3-di-tert-butylimidazol-2-one and 1,3-di-tert-butylimidazolin-2-ylidene was established by single crystal X-ray diffraction. The co-crystal is the product of the oxidation-hydrolysis of the 1,3-di-tert-butylimidazolin-2-ylidene complex with AlH3.

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Funding

This work was carried out with the financial support of St. Petersburg State University (grant SPbSU-DFG 12.65.44.2017, enterprise 6 12.42.719.2017 and 28875246).

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Authors and Affiliations

  1. St. Petersburg State University, 199043, St. Petersburg, Russia

    A. M. Chernysheva & A. Yu. Timoshkin

  2. University of Regensburg, 93040, Regensburg, Germany

    A. V. Virovets & E. V. Peresypkina

Authors
  1. A. M. Chernysheva
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  2. A. V. Virovets
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  3. E. V. Peresypkina
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  4. A. Yu. Timoshkin
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Correspondence to A. Yu. Timoshkin.

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Chernysheva, A.M., Virovets, A.V., Peresypkina, E.V. et al. Structure of the Product of 1,3,5,7-Tetra-tert-butyloctahydro-1H,4аH-imidazo[4′,5′:5,6]dioxino[2,3-d]imidazole Cocrystallization with 1,3-Di-tert-butylimidazol-2-one and 1,3-Di-tert-butylimidazolin-2-ylidene. Russ J Gen Chem 90, 1625–1629 (2020). https://doi.org/10.1134/S1070363220090066

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