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Alkyl 3-Nitroacrylates in the Reactions with Heterocyclic CH Acids

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Abstract

The reactions of alkyl 3-nitroacrylates with certain heterocyclic CH acids such as 1,3-dimethylpyrimidine-2,4,6(1Н,3Н,5Н)-trione, 5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, 4-hydroxy-6-methyl-2H-pyran-2-one, and 4-hydroxy-2H-chromen-2-one occur in the presence of the Rodionov catalyst to form the Michael adducts. The products structure has been confirmed by 1H, 13C{1H}, and 1Н-15N HMBC NMR as well as IR spectroscopy methods.

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Funding

This study was financially supported by the Ministry of Education of Russia within the framework of the governmental task (project no. FSZN-2020-0026). Physico-chemical investigations were performed using the equipment of the Center for Collective Usage, Department of Chemistry, Herzen State Pedagogical University of Russia.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, 191186, St. Petersburg, Russia

    V. V. Pelipko, M. A. Kuritsynа, R. I. Baichurin & S. V. Makarenko

Authors
  1. V. V. Pelipko
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  2. M. A. Kuritsynа
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  3. R. I. Baichurin
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  4. S. V. Makarenko
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Correspondence to S. V. Makarenko.

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To the 80th anniversary of V.M. Berestovitskaya

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Pelipko, V.V., Kuritsynа, M.A., Baichurin, R.I. et al. Alkyl 3-Nitroacrylates in the Reactions with Heterocyclic CH Acids. Russ J Gen Chem 90, 1398–1402 (2020). https://doi.org/10.1134/S1070363220080034

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