Skip to main content
SpringerLink
Log in

Complexing and Acid-Base Properties of 5,10,15,20-Tetraphenylporphine Oxaderivatives

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

The acid-base properties of 5,10,15,20-tetraphenyl-21-oxaporphyrin and 5,10,15,20-tetraphenyl-21,23-dioxaporphyrin have been studied by means of spectrophotometric titration. The parameters of electronic absorption spectra and the concentration ranges of the existence of the obtained forms have been determined. Kinetics of the formation of complexes of 5,10,15,20-tetraphenylporphine oxa derivatives with copper at 288–308 K has been studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme
Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Berezin, B.D., Coordination Compounds of Porphyrins and Phthalocyanines, New York: John Wiley & Sons, 1981, p. 323.

  2. Buchler, J.W., in Porphyrins, Dolphin, D., Ed., New York: Academic Press, 1978, vol. 1, p. 389.

  3. Tarasevich, M.R. and Radyushkina, M.R., Kataliz i elektrokataliz metalloporfirinami (Catalysis and Electrocatalysis by Metal Porphyrins), Moscow: Mir, 1982, p. 168.

  4. Senge, M.O., in The Porphyrin Handbook , Kadish, K.M., Smith, K.M., and Guilard, R., Eds., San Diego: Academic Press, 1999, vol. 1, p. 239.

  5. da G.H. Vicente, M., and Smith, K.M., Curr. Org. Synth., 2014, vol. 11, no. 1, p. 3. https://doi.org/10.2174/15701794113106660083

  6. Syrbu, S.A., Ageeva, T.A., Kolodina, E.A., Semeykin, A.S., and Koifman, O.I., J. Porph. Phthal., 2006, vol. 10, nos. 4–6, p. 885. https://doi.org/10.1142/S1088424606000235

  7. Syrbu, S.A., Pukhovskaya, S.G., Nam, T.D., Ivanova, Yu.B., and Razumov, M.I., Macroheterocycles, 2019, vol. 12, no. 2, p. 135. https://doi.org/10.6060/mhc190557s

    Article  CAS  Google Scholar 

  8. Rocheva, T.K., Shevchenko, O.G., Mazaletskaya, L.I., Sheludchenko, N.I., and Belykh, D.V., Macroheterocycles, 2018, vol. 11, no. 1, p. 95. https://doi.org/10.6060/mhc170302b

    Article  CAS  Google Scholar 

  9. Funktsional’nye materialy na osnove tetrapirrol’nykh makrogeterotsiklicheskikh soedinenii (Functional Materials Based on Tetrapyrrole Macroheterocyclic Compounds), Koifman, O.I., Ed., Moscow: LENAND, 2019.

  10. Ivanova, Yu.B., Pukhovskaya, S.G., Mamardashvili, N.Zh., Koifman, O.I., and Kruk, M.M., J. Mol. Liq., 2019, vol. 275, p. 491. https://doi.org/10.1016/j.molliq.2018.11.107

    Article  CAS  Google Scholar 

  11. Latos-Grażyński, L., in The Porphyrin Handbook, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., New York: Academic Press, 2000, vol. 2, p. 36.

  12. Syrbu, S.A., Pukhovskaya, S.G., Ivanova, Yu.B., and Vashurin, A.S., Russ. J. Gen. Chem., 2019, vol. 89, no. 2, p. 255. https://doi.org/10.1134/S1070363219020142

  13. Lisowski, J., Grzeszczuk, M., and Latos-Grażyński, L., Inorg. Chim. Acta, 1989, vol. 161, no. 153. https://doi.org/10.1016/S0020-1693(00)83086-8

  14. Pandian, R.P. and Chandrashekar, T.K., Inorg. Chem., 1994, vol. 33, p. 3317. https://doi.org/10.1021/ic00093a020

  15. Pandian, R.P. and Chandrashekar, T.K, J. Chem. Soc. Dalton Trans., 1993, vol. 1, p. 119. https://doi.org/10.1039/dt9930000119

  16. Chmielewski, P.J., Latos-Grażyński, L., Olmstead, M.M., and Balch, A.L., Chem. Eur. J., 1997, vol. 3, p. 268. https://doi.org/10.1002/chem.19970030216

  17. Chmielewski, P.J. and Latos-Grażyński, L., Inorg. Chem., 1998, vol. 37, p. 4179. https://doi.org/10.1021/ic971387i

    Article  CAS  PubMed  Google Scholar 

  18. Sridevi, B., Narayanan, S.J., Srinivasan, A., Chandrashekar, T.K., and Subramanian, J., J. Chem. Soc. Dalton Trans., 1998, vol. 12. P., 1979. https://doi.org/10.1039/a801934g

  19. Pawlicki, M., Kańska, I., and Latos-Grażyński, L., Inorg. Chem., 2007, vol. 46, no. 16, p. 6575. https://doi.org/10.1021/ic700631t

    Article  CAS  PubMed  Google Scholar 

  20. Broadhurst, M.J., Grigg, R., and Johnson, A.W., J. Chem. Soc. (D), 1969, vol. 1480. https://doi.org/10.1039/C29690001480

  21. Broadhurst, M.J., Grigg, R., and Johnson, A.W., J. Chem. Soc. (D), 1970, vol. 807. https://doi.org/10.1039/C29700000807

  22. Broadhurst, M.J. and Grigg, R., J. Chem. Soc. (С), 1971, p. 3681. https://doi.org/10.1039/J3971000368.1

  23. Latos-Grażyński, L., Lisowski, J., Olmstead, M.M., and Balch, A.L., J. Am. Chem. Soc., 1987, vol. 109, p. 4428. https://doi.org/10.1021/ja00248a067

  24. Latos-Grażyński, L., Lisowski, J., Olmstead, M.M., and Balch, A.L., Inorg. Chem., 1989, vol. 28, no. 22, p. 4065. https://doi.org/10.1021/ic00321a005

    Article  Google Scholar 

  25. Latos-Grażyński, L., Lisowski, J., Olmstead, M.M., and Balch, A.L., Inorg. Chem .., 1989, vol. 28, p. 1183. https://doi.org/10.1021/ic00305a032

    Article  Google Scholar 

  26. Latos-Grażyński, L., Lisowski, J., Chmielewski, M., Grzeszczuk, M., Olmstead, M.M., and Balch, A.L., Inorg. Chem., 1994, vol. 33, p. 192. https://doi.org/10.1021/ic00080a004

    Article  Google Scholar 

  27. Latos-Grażyński, L., Pacholska, E., Chmielewski, M., Grzeszczuk, M., Olmstead, M.M., and Balch, A.L., Inorg. Chem., 1996, vol. 35, p. 556. https://doi.org/10.1021/ic950329z

    Article  Google Scholar 

  28. Gross, Z., Saltsman, I., Pandian, R.P., and Barzilay, C., Tetrahedron Lett., 1997, vol. 38, p. 2383. https://doi.org/10.1016/S0040-4039(97)00357-2

    Article  CAS  Google Scholar 

  29. Andrianov, V.G. and Malkova, O.V., Macroheterocycles, 2009, vol. 2, no. 2, p. 130. https://doi.org/10.6060/mhc2009.2.130

    Article  CAS  Google Scholar 

  30. Tagawa, K., Mori, S., Okujima, T., and Takas, M., Tetrahedron, 2017, vol. 73, p. 794. https://doi.org/10.1016/j.tet.2016.12.067

    Article  CAS  Google Scholar 

  31. Pukhovskaya, S.G., Ivanova, Yu.B., Nam, D.T., and Vashurin, A.S., Russ. J. Phys. Chem., 2014, vol. 88, no. 10, p. 1670. https://doi.org/10.1134/S0036024414100288

    Article  CAS  Google Scholar 

  32. Kuvshinova, E.M., Pukhovskaya, S.G., Golubchikov, O.A., and Berezin, B.D., Koord. Khim., 1993, vol. 19, no. 8, p. 630.

    CAS  Google Scholar 

  33. Gordon, A. and Ford, R., The Chemist’s Companion, New York: Wiley, 1972.

  34. Weissberger, A., Proskauer, E., and Riddic, J., Organic Solvents, New York: Interscience Publishers, 1955

  35. Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie reaktivy (Pure Chemicals), Moscow: Khimiya, 1974.

  36. Ivanova, Yu.B., Sheinin, V.B., and Mamardashvili, N.Zh., Russ. J. Gen. Chem., 2007, vol. 77, no. 8, p. 1458. https://doi.org/10.1134/S1070363207080270

    Article  CAS  Google Scholar 

  37. Nam, D.T., Pukhovskaya, S.G., Ivanova, Y.B., Liulkovich, L.S., Semeikin, A.S., Syrbu, S.A., and Kruk, M.M., J. Incl. Phenom. Macrocycl. Chem., 2017, vol. 89, nos. 3–4, p. 325. https://doi.org/10.1007/s10847-017-0758-9

    Article  CAS  Google Scholar 

  38. Ivanova, Yu.B., Churakhina, Yu.I., and Mamardashvili, N.Zh., Russ. J. Gen. Chem., 2008, vol. 78, no. 4, p. 673. https://doi.org/10.1134/S1070363208040269

    Article  CAS  Google Scholar 

Download references

Funding

This study was financially supported by the Russian Foundation for Basic Research (grant no. 19-03-00214 А) and performed using the equipment of the Center for Collective Usage “Upper Volga Regional Center for Physico-Chemical Investigation.”

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, 153000, Ivanovo, Russia

    S. G. Pukhovskaya, A. O. Plotnikova, D. A. Shelekhova & A. N. Kiselev

  2. G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045, Ivanovo, Russia

    Yu. B. Ivanova, A. N. Kiselev & S. A. Syrbu

Authors
  1. S. G. Pukhovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. B. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. O. Plotnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. A. Shelekhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. N. Kiselev
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. A. Syrbu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. G. Pukhovskaya.

Ethics declarations

No conflict of interest was declared by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pukhovskaya, S.G., Ivanova, Y.B., Plotnikova, A.O. et al. Complexing and Acid-Base Properties of 5,10,15,20-Tetraphenylporphine Oxaderivatives. Russ J Gen Chem 90, 1292–1297 (2020). https://doi.org/10.1134/S1070363220070154

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363220070154

Keywords:

Search

Navigation