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Gas-Phase and Liquid-Phase Hydrogenation of Acetylene in Lean and Enriched Mixtures over Supported Modified Palladium Catalysts

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

The results of studies on selective hydrogenation of acetylene to ethylene over bimetallic palladium-containing catalysts were summarized. Regular and specific features of the catalyst action in gas-phase hydrogenation of traces of acetylene in the acetylene-ethylene mixture produced by pyrolysis of petroleum feedstock, as well as in liquid-phase hydrogenation of mixtures enriched in acetylene and hydrogen were analyzed. The advantages of ethylene production by liquid-phase hydrogenation of acetylene were shown, and ways of increasing the selectivity to ethylene in this process were considered.

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  1. Center of New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 644040, Omsk, Russia

    D. V. Glyzdova, D. A. Shlyapin & P. G. Tsyrul’nikov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    N. S. Smirnova

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Glyzdova, D.V., Smirnova, N.S., Shlyapin, D.A. et al. Gas-Phase and Liquid-Phase Hydrogenation of Acetylene in Lean and Enriched Mixtures over Supported Modified Palladium Catalysts. Russ J Gen Chem 90, 1120–1140 (2020). https://doi.org/10.1134/S1070363220060298

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