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Synthesis of Verdazyl Radicals with Different Number of Methylene Fragments in the Internal Conjugated Diyne Moiety and Their Ability to Solid-State Polymerization

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Abstract

Verdazyl radicals have been obtained from non-symmetric alkadiynyl ethers ofp-hydroxybenzaldehyde. Using these radicals, the effect of the distance between the conjugated diyne fragment and the bulky tetrazinyl substituent on the ability to solid-state polymerization under UV irradiation has been studied. It has been shown that the rate of solid-state polymerization (accompanied by the preservation of the radical site) is increased with an increase in the number of methylene groups in the alkadiyne fragment.

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Notes

  1. Cherry coloration of formazans 4a, 4b disappeared during 15 min, and the mixture became clay-colored.

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Authors and Affiliations

  1. N.P. Ogarev Mordovia State University, 430005, Saransk, Russia

    S. G. Kostryukov, M. K. Pryanichnikova, A. Sh. Kozlov, A. A. Burtasov & B. S. Tanaseichuk

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  1. S. G. Kostryukov
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  2. M. K. Pryanichnikova
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  3. A. Sh. Kozlov
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  4. A. A. Burtasov
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  5. B. S. Tanaseichuk
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Correspondence to S. G. Kostryukov.

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Kostryukov, S.G., Pryanichnikova, M.K., Kozlov, A.S. et al. Synthesis of Verdazyl Radicals with Different Number of Methylene Fragments in the Internal Conjugated Diyne Moiety and Their Ability to Solid-State Polymerization. Russ J Gen Chem 90, 832–838 (2020). https://doi.org/10.1134/S1070363220050126

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  • DOI: https://doi.org/10.1134/S1070363220050126

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