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Polymer Matrix Effect on Nonlinear Optical Response of Composite Materials Doped with a Chromophore Containing a Divinylqunoxaline π-Electron Bridge

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Abstract

The effect of polymer matrices on the nonlinear-optical properties of composite materials with guest chromophores containing a divinylquinoxaline π-electronic bridge has been investigated. Poly(methyl methacrylate) and different methacrylic copolymers as well as epoxy-amine oligomers with azo chromophores in the backbone or as side groups have been used as polymer matrices. The use of a polymer matrix containing carboxylic groups has resulted in significant decrease in the nonlinear-optical coefficient d33 as compared to the case of poly(methyl methacrylate) matrix with a guest chromophore content of 20 wt%. For materials with binary chromophores, d33 values of the studied materials have been higher than for conventional composites.

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REFERENCES

  1. Dalton, L.R., Sullivan, P.A., and Bale, D.H., Chem. Rev., 2010, vol. 110, p. 25. https://doi.org/10.1021/cr9000429

    Article  CAS  PubMed  Google Scholar 

  2. Dalton, L.R., Pure. Appl. Chem., 2004, vol. 76, nos. 7–8, p. 1421. https://doi.org/10.1351/pac200476071421

    Article  CAS  Google Scholar 

  3. Dalton, L.R., Harper, A., Ren, A., Wang, F., Todorova, G., Chen, J., Zhang, C., and Lee, M., Ind. Eng. Chem. Res., 1999, vol. 38., P.8. https://doi.org/10.1021/ie9705970

  4. Sharipova, S.M. and Kalinin, A.A., Chem. Heterocycl. Compd., 2017, vol. 53, p. 36. https://doi.org/10.1007/s10593-017-2017-9

    Article  CAS  Google Scholar 

  5. Yamada, T., Aoki, I., Miki, H., Yamada, C., and Otomo, A., Mater. Chem. Phys., 2013, vol. 139, p. 699. https://doi.org/10.1016/j.matchemphys.2013.02.020

    Article  CAS  Google Scholar 

  6. Banach, M.J., Alexander, M.D., Caracci, S.Jr., and Vaia, R.A., Chem. Mater., 1999, vol. 11, p. 2554. https://doi.org/10.1021/cm9902725

    Article  CAS  Google Scholar 

  7. Abbotto, A., Beverina, L., Bradamante, S., Facchetti, A., Klein, C., Pagani, G.A., Redi-Abshiro, M., and Wortmann, R., Chem. Eur. J., 2003, vol. 9, p. 1991. https://doi.org/10.1002/chem.200204356

    Article  CAS  PubMed  Google Scholar 

  8. Balakina, M.Yu., ChemPhysChem., 2006, vol. 7, no. 10, p. 2115. https://doi.org/10.1002/cphc.200600263

    Article  CAS  PubMed  Google Scholar 

  9. Makowska-Janusik, M., Kityk, I.V., Kulhánek, J., and Bureš, F., J. Phys. Chem. (A), 2011, vol. 115, no. 44, p. 12251. https://doi.org/10.1021/jp2013539

    Article  CAS  Google Scholar 

  10. Makowska-Janusik, M., and Benard, J.-F., J. Phys., 2007, vol. 79, p. 012030. https://doi.org/10.1088/1742-6596/79/1/012030

    Article  CAS  Google Scholar 

  11. Jespersen, K.G., Pedersen, T.G., and Johansen, P.M., J. Opt. Soc. Am. (B), 2003, vol. 20, no. 10, p. 2179. https://doi.org/10.1364/JOSAB.20.002179

    Article  CAS  Google Scholar 

  12. Pedersen, T.G., Jespersen, K., Johansen, P.M., and Wyller, J., J. Opt. Soc. Am. (B), 2002, vol. 19, no. 11, p. 2622. https://doi.org/10.1364/JOSAB.19.002622

    Article  CAS  Google Scholar 

  13. Burland, D.M., Miller, R.D., and Walsh, C.A., Chem. Rev., 1994, vol. 94, no. 1, p. 31. https://doi.org/10.1021/cr00025a002

    Article  CAS  Google Scholar 

  14. Apitz, D., Svanberg, C., Jespersen, K., Pedersen, T.G., and Johansen, P.M., J. Appl. Phys., 2003, vol. 94, no. 10, p. 6263. https://doi.org/10.1063/1.1621725

    Article  CAS  Google Scholar 

  15. Kalinin, A.A., Sharipova, S.M., Burganov, T.I., Levitskaya, A.I., Fominykh, O.D., Vakhonina, T.A., Ivanova, N.V., Khamatgalimov, A.R., Katsyuba, S.A., and Balakina, M.Yu., J. Photochem. Photobiol. (A), 2019, vol. 370, p. 58. https://doi.org/10.1016/j.jphotochem.2018.10.034

    Article  CAS  Google Scholar 

  16. Vakhonina, T.A., Sharipova, S.M., Ivanova, N.V., Fominykh, O.D., Smirnov, N.N., Yakimansky, A.V., and Balakina, M.Y., Proceedings of SPIE, 2011, vol. 7993, p. 799307. https://doi.org/10.1117/12.880944

    Article  CAS  Google Scholar 

  17. Vakhonina, T.А., Ivanova, N.V., Smirnov, N.N., Yakimansky, A.V., Balakina, M.Yu., and Sinyashin, O.G., Mendeleev Commun., 2014, vol. 24, p. 138. https://doi.org/10.1016/j.mencom.2014.04.002

    Article  CAS  Google Scholar 

  18. Nazmieva, G.N., Vakhonina, T.A., Ivanova, N.V., Mukhtarov, A.Sh., Smirnov, N.N., Yakimansky, A.V., Balakina, M.Yu., and Sinyashin, O.G., Eur. Pol. J., 2015, vol. 63, p. 207. https://doi.org/10.1016/j.eurpolymj.2014.12.003

    Article  CAS  Google Scholar 

  19. Nikonorova, N.A., Balakina, M.Yu., Fominykh, O.D., Pudovkin, M.S., Vakhonina, T.A., Diaz-Calleja, R., and Yakimansky, A.V., Chem. Phys. Lett., 2012, vol. 552, p. 114. https://doi.org/10.1016/j.cplett.2012.09.053

    Article  CAS  Google Scholar 

  20. Nikonorova, N.A., Balakina, M.Yu., Fominykh, O.D., Sharipova, A.V., Vakhonina, T.A., Nazmieva, G.N., Castro, R.A., and Yakimansky, A.V., Mater. Chem. Phys., 2016, vol. 181, p. 217. https://doi.org/10.1016/j.matchemphys.2016.06.052

    Article  CAS  Google Scholar 

  21. Balakina, M.Yu., Fominykh, O.D., Vakhonina, T.A., Smirnov, M.A., and Sharipova, A.V., IEEE Transactions on Dielectrics and Electrical Insulation, 2018, vol. 25, no. 3, p. 778. https://doi.org/10.1109/TDEI.2017.007028

    Article  CAS  Google Scholar 

  22. Vakhonina, T.A., Kadyrova, A.A., Sarvarov, T.M., Smirnov, M.A., Ivanova, N.V., Khamatgalimov, A.R., Balakina, M.Yu., and Sinyashin, O.G., Mendeleev Commun., 2018, vol. 28, p. 272. https://doi.org/10.1016/j.mencom.2018.05.014

    Article  CAS  Google Scholar 

  23. Shulyndin, S.V., Vakhonina, T.A., Ivanova, N.V., Gubanov, E.F., Ustyugov, A.N., Fominykh, O.D., Estrina, G.A., Rozenberg, B.A., and Zuev, M.B., Polym. Sci. (A), 2005, vol. 47, no. 8, p. 808.

    Google Scholar 

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Funding

T. A. Vakhonina, A. A. Kalinin, and A. A. Kadyrova are grateful to the Russian Science Foundation (project no. 16-13-10215) for financial support of the investigation of nonlinear optical activity of composite materials with binary chromophores.

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Authors and Affiliations

  1. A.E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”, 420088, Kazan, Russia

    T. A. Vakhonina, A. A. Kalinin, N. V. Ivanova, A. A. Kadyrova, S. M. Sharipova, M. A. Smirnov, A. Sh. Mukhtarov & M. Yu. Balakina

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  1. T. A. Vakhonina
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  2. A. A. Kalinin
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  3. N. V. Ivanova
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  4. A. A. Kadyrova
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  5. S. M. Sharipova
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  6. M. A. Smirnov
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  7. A. Sh. Mukhtarov
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  8. M. Yu. Balakina
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Correspondence to T. A. Vakhonina.

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To the 80th Anniversary of R.A. Cherkasov

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Vakhonina, T.A., Kalinin, A.A., Ivanova, N.V. et al. Polymer Matrix Effect on Nonlinear Optical Response of Composite Materials Doped with a Chromophore Containing a Divinylqunoxaline π-Electron Bridge. Russ J Gen Chem 90, 448–453 (2020). https://doi.org/10.1134/S1070363220030184

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  • DOI: https://doi.org/10.1134/S1070363220030184

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