Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of Dipotassium Salts of N-Alkyl-N-{[O-alkoxy(hydroxy)phosphoryl]methyl}ditiocarbamic Acids

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

A one-pot method for the synthesis of dipotassium salts of N-alkyl-N-{[O-alkoxy(hydroxy)phosphoryl]methyl}dithiocarbamic acids has been elaborated. Dipotassium salts of N-isopropyl-, N-butyl-, and N-cyclohexyl-N-{[hydroxy(O-ethoxy)phosphoryl]methyl}dithiocarbamic acids as well as N-{[O-butoxy(hydroxy)phosphoryl]methyl}-N-(2-methoxyethyl)dithiocarbamic acid have been synthesized and isolated. Crystal and molecular structure of the latter compound have been elucidated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme
Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Byr’ko, V.M., Ditiokarbamaty (Dithiocarbamates), Moscow: Nauka, 1984.

  2. Bai, Z., Zhang, J., Zhang, Q., Zhang, T., Li, J., Zhao, Q., Wang, Z., He, D., Cheng, J., Zhang, J., and Liu, B., Eur. J. Med. Chem., 2018, vol. 159, p. 339. https://doi.org/10.1016/j.ejmech.2018.10.004

    Article  CAS  PubMed  Google Scholar 

  3. Criado, J.J., Lopez-Arias, J.A., Macias, B., FernandezLago, L.R., and Salas, J.M., Inorg. Chim. Acta, 1992, vol. 193, no. 2, p. 229. https://doi.org/10.1016/s0020-1693(00)80357-6

    Article  CAS  Google Scholar 

  4. Pustelny, K., Bielanska, J., Plonka, P.M., Rosen, G.M., and Elas, M., Nitric Oxide, 2007, vol. 16, no. 2, p. 202. https://doi.org/10.1016/j.niox.2006.10.002

    Article  CAS  PubMed  Google Scholar 

  5. Dennis, K.E. and Valentine, W.M., Chem. Res. Toxicol., 2015, vol. 28, no. 4, p. 682. https://doi.org/10.1021/tx500450x

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  6. Valentine, H.L., Viquez, O.M., Amarnath, K., Amarnath, V., Zyskowski, J., Kassa, E.N., and Valentine, W.M., Chem. Res. Toxicol., 2009, vol. 22, no. 1, p. 218. https://doi.org/10.1021/tx8003714

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  7. Srivastava, A.K., J. Indian Chem. Soc., 2009, vol. 86, no. 3, p. 281.

    CAS  Google Scholar 

  8. Giovagnini, L., Sitran, S., Montopoli, M., Caparrotta, L., Corsini, M., Rosani, C., Zanello, P., Dou, Q.P., and Fregona, D., Inorg. Chem., 2008, vol. 47, no. 14, p. 6336. https://doi.org/10.1021/ic800404e

    Article  CAS  PubMed  Google Scholar 

  9. Aksenin, N.S., Bukharov, M.S., Garifzyanov, A.R., Serov, N.Yu., Gilyazetdinov, Je.M., Mirzayanov, I.I., and Shtyrlin, V.G., Sb. mater. XIII Vserossiiskoi molodezhnoi nauchno-innovatsionnoi shkoly “Matematika i matematicheskoe modelirovanie” (Coll. Mater. XIII All-Russ. Youth Scientific and Innovative School “Mathematics and Mathematical Modeling”), Sarov, 2019, p. 239.

  10. Tlahuext, H., Rosas-Valdéz, E., López-Cardoso, M., Román-Bravo, P., Vargas-Pineda, G., Montiel-Palma, V., Cotero-Villegas, A.M., Pérez-Redondo, M.C., and Cea-Olivares, R., J. Mol. Struct., 2018, vol. 1169, p. 68. https://doi.org/10.1016/j.molstruc.2018.05.029

    Article  CAS  Google Scholar 

  11. Bruker. APEX3. Crystallography Software Suite, Bruker AXS, Inc., Madison, WI, USA, 2016.

  12. Bruker. SAINT. Crystallography Software Suite, Bruker AXS, Inc., Madison, WI, USA, 2016.

  13. Krause, L., Herbst-Irmer, R., Sheldrick, G.M., and Stalk, D.J., Appl. Crystallogr., 2015, vol. 48, p. 3. https://doi.org/10.1107/S1600576714022985

    Article  CAS  Google Scholar 

  14. Sheldrick, G.M., Acta Crystallogr. (A), 2015, vol. 71, p. 3. https://doi.org/10.1107/S2053273314026370

    Article  CAS  Google Scholar 

  15. Sheldrick, G.M., Acta Crystallogr. (A), 2008, vol. 64, p. 112. https://doi.org/10.1107/S0108767307043930

    Article  CAS  Google Scholar 

  16. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Cryst., 2009, vol. 42, p. 339. https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  17. Zakharov, S.V., Nuriazdanova, G.Kh., Garifzyanov, A.R., Galkin, V. I., and Cherkasov, R.A., Russ. J. Gen. Chem., 2004, vol. 74, no. 6, p. 873. https://doi.org/10.1023/B:RUGC.0000042422.61124.b3

    Article  CAS  Google Scholar 

Download references

Funding

This study was financially supported by the Russian Foundation for Basic Research (project 18-33-20072).

Author information

Authors and Affiliations

  1. A.M. Butlerov Institute of Chemistry, Kazan Federal University, 420008, Kazan, Russia

    I. I. Mirzayanov, A. R. Garifzyanov & V. G. Shtyrlin

  2. A.E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center Kazan Scientific Center of the Russian Academy of Sciences, 420088, Kazan, Russia

    D. R. Islamov

Authors
  1. I. I. Mirzayanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. R. Garifzyanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. R. Islamov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Shtyrlin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. I. Mirzayanov.

Ethics declarations

No conflict of interest was declared by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mirzayanov, I.I., Garifzyanov, A.R., Islamov, D.R. et al. Synthesis and Crystal Structure of Dipotassium Salts of N-Alkyl-N-{[O-alkoxy(hydroxy)phosphoryl]methyl}ditiocarbamic Acids. Russ J Gen Chem 90, 381–384 (2020). https://doi.org/10.1134/S1070363220030081

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363220030081

Keywords:

Search

Navigation