Skip to main content
SpringerLink
Log in

Synthesis and Photocatalytic Activity of Cerium(IV) Fibrous Nanostructures

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The method using cellulose as a template was proposed for the synthesis of fibrous structures consisting of cerium(IV) oxide nano-sized particles. The chemical composition and morphology of the samples as functions of the annealing temperature were studied by X-ray diffraction analysis, IR spectroscopy, and scanning electron microscopy. It was shown that CeO2 particles obtained from Ce(NO3)3 by the template synthesis at 800°C have the highest photocatalytic activity in the photodestruction of methyl orange (pH = 3.5, acetate buffer) and phenol. It was revealed that CeO2 particles exhibit photoprotective properties in the hydrotartrate buffer solution of methyl orange.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Shapovalov, V.I., Glass Phys. Chem., 2010, vol. 36, no. 2, p. 121. https://doi.org/10.1134/S108765961002001X

    Article  CAS  Google Scholar 

  2. Linsebigler, A.L., Chem. Rev., 1995, vol. 95, no. 3, p. 735. https://doi.org/10.1021/cr00035a013

    Article  CAS  Google Scholar 

  3. Pugachevskii, M.A., Nanotechnologies in Russia, 2013, vol. 8, nos. 7–8, p. 432. https://doi.org/10.1134/S1995078013040125

    Article  Google Scholar 

  4. Alyakhnovich, N.S. and Novikov, D.K., Immunopathology, Allergology, Infectology, 2015, no. 1, p. 71. https://doi.org/10.14427/jipai.2015.1.71

    Article  Google Scholar 

  5. Jaroenworaluck, A., Sunsaneeyametha, W., Kosachan, N., and Stevens, R., Surface and Interface Analysis, 2006, vol. 38, no. 4, p. 473. https://doi.org/10.1002/sia.2313

    Article  CAS  Google Scholar 

  6. Wamer, W.G., Yin, J.J., and Wei, R.R., Free Rad. Biol. Med., 1997, vol 23, no. 6, p. 851. https://doi.org/10.1016/S0891-5849(97)00068-3

    Article  Google Scholar 

  7. Li, R., Yabe, S., Yamashita, M., Momose, S., Yoshida, S., Yin Shu, and Sato, T., Mat. Chem. Phys., 2002, vol. 75, p. 39. https://doi.org/10.1016/S0254-0584(02)00027-5

    Article  CAS  Google Scholar 

  8. Li, R., Yabe, S., Yamashita, M., Momose, S., Yoshida, S., Yin Shu, and Sato, T., Solid State Ionics, 2002, vol. 151, p. 235. https://doi.org/10.1016/S0167-2738(02)00715-4

    Article  CAS  Google Scholar 

  9. Ivanov, V.K., Shcherbakov, A.B., Baranchikov, A.E., and Kozik, V.V., Nanokristallichtskii dioksid tseriya: svoistva, poluchenie, primenenie (Nanocrystalline Cerium Dioxide: Properties, Preparation, Application}, Tomsk: Izd Tomsk. Univer., 2013.

  10. Zhong, L. and Xiangdong, F., J. Phys. Chem., 2003, p. 13563. https://doi.org/10.1021/jp036815m

  11. Ivanov, V.K., Polezhaeva, O.S., Gil’, D.O., Tret’yakov, Yu.D., and Kopitsa, G.P., Dokl. Akad. Nauk, 2009, vol. 426, no. 2, p. 131. https://doi.org/10.1134/S0012500809060056

    Article  CAS  Google Scholar 

  12. Zhijian, L., Shuyu, G., Chenggong, H., and Zhengbing, X., J. Mater. Sci., 2016, p. 2146. https://doi.org/10.1007/s10854-015-4004-1

  13. Polezhaeva, O.S., Yaroshinskaya, N.V., and Ivanov, V.K., Russ. J. Inorg. Chem., 2007, vol. 52, no. 8, p. 1184. https://doi.org/10.1134/S0036023607080049

    Article  Google Scholar 

  14. Tuyen, L.T.T., Khieu, D.Q., Long, H.T., and Quang, D.T., J. Nanomater., 2016, vol. 2016. https://doi.org/10.1155/2016/8682747

  15. Ravishankar, T.N., Ramakrishnappa, T., Nagaraju, G., and Rajanaika, H., Chem. Open., 2015, vol. 4, p. 146. https://doi.org/10.1002/open.201402046

    Article  CAS  Google Scholar 

  16. Liu, I.T., Hon, M.H., and Teoh, L.G., J. Electr. Mater., 2013, vol. 42, no. 8, p. 2537. https://doi.org/10.1007/s11664-013-2617-9

    Article  CAS  Google Scholar 

  17. Vakhrushev, A.Y., Gorbunova, V.V., Boitsova, T.B., Stozharov, V.M., and Lukanina, T.L., Inorg. Mater., 2013, vol. 49, no. 12, p. 1209. https://doi.org/10.7868/S0002337X13120142

    Article  CAS  Google Scholar 

  18. Chen, L., Fleming, P., Morris, V., Holmes, J.D., and Morris, M.A., J. Phys. Chem. (C), 2010, vol. 114, p. 12909. https://doi.org/10.1021/jp1031465

    Article  CAS  Google Scholar 

  19. Ma, R., Islam, M.J., Reddy, D.A., and Kim, K.T., Ceram. Int., 2016, vol. 42, no. 16, p. 18495. https://doi.org/10.1016/j.ceramint.2016.08.186

    Article  CAS  Google Scholar 

  20. Zholobak, N.M., Ivanov, V.K., Shcherbakov, A.B., Shaporev, A.S., Polezhaeva, O.S., Baranchikov, A.Y., Spivak, N.Y., and Tretyakov, Yu.D., J. Photochem. Photobiol. (B), 2011, vol. 102, p. 32. https://doi.org/10.1016/j.jphotobiol.2010.09.002

    Article  CAS  Google Scholar 

  21. Sobczynski, A., Duczmal, Ł., and Zmudzinski, W., J. Mol. Catal. (A), 2004, vol. 213, no. 2, p. 225. https://doi.org/10.1016/j.molcata.2003.12.006

    Article  CAS  Google Scholar 

  22. Guo, J., Chen, X., Shi, Y., Lan, Y., Qin, C., PloS One, 2015, vol. 10, no. 8. С. 1. https://doi.org/10.1371/journal.pone.0134298

  23. Guo, J., Du, Y., Lan, Y., and Mao, J., J. Hazard. Mater., 2011, vol. 186, nos. 2–3, p. 2083. doi: 10.1016/j.jhazmat.2010.12.112

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, 191186, St. Petersburg, Russia

    А. А. Volkov, T. B. Boitsova, V. M. Stozharov & E. I. Isaeva

Authors
  1. А. А. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. B. Boitsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Stozharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. I. Isaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. I. Isaeva.

Ethics declarations

No conflict of interest was declared by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Volkov, А.А., Boitsova, T.B., Stozharov, V.M. et al. Synthesis and Photocatalytic Activity of Cerium(IV) Fibrous Nanostructures. Russ J Gen Chem 90, 277–282 (2020). https://doi.org/10.1134/S1070363220020188

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363220020188

Keywords:

Search

Navigation