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Single-Crystal X-Ray Diffraction Studies in a Series of 5-Pentafluorophenyl-2,2'-bipyridines and Their Fused Analogs

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Abstract

Structure of three 6-aryl-5-pentafluorophenyl-2,2'-bipyridines has been studied by means of single-crystal X-ray diffraction analysis. The effect of some functional fragments on the structural organization of compounds, in particular, donor and acceptor substituents in the aryl moiety, as well as annulated benzene and cyclopentane rings on the molecular structure and crystal packing of pentafluorophenyl-modified 2,2'-bipyridine ligand systems has been analyzed.

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REFERENCES

  1. Burger, M. and Lindvall, M., US Patent 195980, 2011.

  2. Patel, M.N., Bhatt, B.S., and Dosi, P.A., Z. Anorg. Allg. Chem., 2012, vol. 638, p. 152. https://doi.org/10.1002/zaac.201100307

    Article  CAS  Google Scholar 

  3. US Patent 20150307470, 2015.

  4. Tang, M.-C., Chan, A.K.W., Chan, M.-Y., and Yam, V.W.W., Top Curr. Chem., 2016, vol. 374, p. 46. https://doi.org/10.1007/s41061-016-0046-y

    Article  CAS  Google Scholar 

  5. Gildea, L.F. and Williams, J.A.G., in Organic Light-Emitting Diodes (OLEDs) Materials, Devices and Applications, Buckley, A., Ed., Cambridge: Woodhead Publishing, 2013, p. 77. https://doi.org/10.1533/9780857098948.1.77

  6. Zaen, R., Kim, M., Park, K.-M, Lee, K.H., Lee, J.Y., and Kang, Y., Dalton Trans., 2019, vol. 48, p. 9734. https://doi.org/10.1039/C9DT00596J

    Article  CAS  PubMed  Google Scholar 

  7. Kopchuk, D.S., Krinochkin, A.P., Kozhevnikov, D.N., and Slepukhin, P.A., Polyhedron, 2016, vol. 118, p. 30. https://doi.org/10.1016/j.poly.2016.07.025

    Article  CAS  Google Scholar 

  8. Elinson, M.N., Vereshchagin, A.N., Anisina, Y.E., Krymov, S.K., Fakhrutdinov, A.N., Goloveshkin, A.S., and Egorov, M.P., Mol. Divers., 2019, p. 1. https://doi.org/10.1007/s11030-019-09968-x

  9. Moseev, T.D., Varaksin, M.V., Gorlov, D.A., Nikiforov, E.A., Kopchuk, D.S., Starnovskaya, E.S., Khasanov, A.F., Zyryanov, G.V., Charushin, V.N., and Chupakhin, O.N., J. Fluor. Chem., 2019, vol. 224, p. 89. https://doi.org/10.1016/j.jfluchem.2019.05.008

    Article  CAS  Google Scholar 

  10. Sheldrick, G.M., Acta Crystallogr. (A), 2008, vol. 64, p. 112. https://doi.org/10.1107/S0108767307043930

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

This study was financially supported by the Russian Foundation for Basic Research (project 18-33-00226). X-ray diffraction experiments were performed using the equipment of the Center for Collective Usage “Spectroscopy and Analysis of Organic Compounds,” Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences.

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Correspondence to G. V. Zyryanov.

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Moseev, T.D., Varaksin, M., Starnovskaya, E.S. et al. Single-Crystal X-Ray Diffraction Studies in a Series of 5-Pentafluorophenyl-2,2'-bipyridines and Their Fused Analogs. Russ J Gen Chem 90, 235–237 (2020). https://doi.org/10.1134/S1070363220020115

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  • DOI: https://doi.org/10.1134/S1070363220020115

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